A new equation of state based on hole theory: mixtures

被引：1
|
作者：
Park, J
Hong, M
Kim, H [1 ]
机构：
[1] Seoul Natl Univ, Sch Chem Engn, Seoul 151742, South Korea
[2] Kumho Chem, Ctr Res & Dev, Ulsan 680140, GwangyeikSi, South Korea
来源：
FLUID PHASE EQUILIBRIA | 1999年 / 161卷 / 02期
关键词：
equation of state; statistical mechanics; polymer blend; hole theory; mixture;
D O I：
10.1016/S0378-3812(99)00190-9
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
In this paper, our previous work on the equation of state (EOS) based on hole theory was applied to polymer blend, that is the Pressure-Volume-Temperature (PVT) behavior of polymer blend. For the PPO/PS blend, the EOS developed by us shows good results in describing the PVT surface with or without binary parameters, But the binary parameters for the segmental energy is more important to explain the mixture properties from the pure component properties than that for segmental volume. When compared with Simha-Somcynsky (SS) model, this EOS shows better results than SS model for the entire range of weight fraction, (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：265 / 270
页数：6
相关论文
共 50 条
  • [31] Calculation of Molar Volume of Mixtures of Krypton with Argon and Xenon from the Statistical-Mechanical Based Equation of State
    Haghighi, Behzad
    Ghasemi, Hamid
    Niafari, Maryam
    Papari, Mohammad Mehdi
    ASIAN JOURNAL OF CHEMISTRY, 2009, 21 (05) : 3567 - 3576
  • [32] Theoretical Formulism of Viscosity of Liquid Mixtures Using Generalized Hole Theory-A New Approach
    Sanguri, Vinay
    Chandra, Prakash
    Dwivedi, D. K.
    Sethi, Rupali
    Pandey, J. D.
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES INDIA SECTION A-PHYSICAL SCIENCES, 2013, 83 (03) : 225 - 231
  • [33] Analytic equation of state for Lennard-Jones fluids based on the Ross variational perturbation theory
    Sun, JX
    Cai, LC
    Wu, Q
    Jing, FQ
    INTERNATIONAL JOURNAL OF THERMOPHYSICS, 2003, 24 (06) : 1637 - 1650
  • [34] New version of Tao-Mason equation of state: application to refrigerant fluid mixtures
    Alavianmehr, M. M.
    Mehrayin, O.
    Kiani, M.
    Moghadasi, J.
    HIGH TEMPERATURES-HIGH PRESSURES, 2018, 47 (04) : 285 - 298
  • [35] Analytic Equation of State for Lennard-Jones Fluids Based on the Ross Variational Perturbation Theory
    Jiuxun Sun
    LingCang Cai
    Qiang Wu
    Fuqian Jing
    International Journal of Thermophysics, 2003, 24 : 1637 - 1650
  • [36] Molecular thermodynamic theory for polymer systems - III. Equation of state for chain-fluid mixtures
    Liu, HL
    Hu, Y
    FLUID PHASE EQUILIBRIA, 1997, 138 (1-2) : 69 - 85
  • [37] Critical temperatures and pressures for hydrocarbon mixtures from an equation of state with renormalization-group theory corrections
    Jiang, JW
    Prausnitz, JM
    FLUID PHASE EQUILIBRIA, 2000, 169 (02) : 127 - 147
  • [38] Equation of state for the Lennard-Jones fluid based on the perturbation theory
    Betancourt-Cardenas, F. F.
    Galicia-Luna, L. A.
    Sandler, S. I.
    FLUID PHASE EQUILIBRIA, 2008, 264 (1-2) : 174 - 183
  • [39] Phase equilibria study of Lennard-Jones mixtures by an analytical equation of state
    Tang, YP
    Lu, BCY
    FLUID PHASE EQUILIBRIA, 1999, 165 (02) : 183 - 196
  • [40] Morse oscillator equation of state: An integral equation theory based with virial expansion and compressibility terms
    Al-Raeei, Marwan
    HELIYON, 2022, 8 (04)
12345