A Bifunctional Ligand Enables Gold-Catalyzed Hydroarylation of Terminal Alkynes under Soft Reaction Conditions

被引：22

作者：

Li, Ting ^{[1
,2
]}

Yang, Yuhan ^{[1
]}

Luo, Baomin ^{[1
]}

Li, Bo ^{[1
]}

Zong, Luyi ^{[1
]}

Kong, Weiguang ^{[1
]}

Yang, Hao ^{[1
]}

Cheng, Xinpeng ^{[2
]}

Zhang, Liming ^{[2
]}

机构：

[1] Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Nanyang 473061, Henan, Peoples R China

[2] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

来源：

ORGANIC LETTERS | 2020年 / 22卷 / 15期

关键词：

INTRAMOLECULAR HYDROARYLATION; INDUSTRIAL PERSPECTIVE; ORTHO-ALKENYLATION; COUNTER ANIONS; PHENOLS; PLATINUM; HYDROPHENOXYLATION; HETEROARENES; VINYLATION; EFFICIENT;

D O I：

10.1021/acs.orglett.0c02130

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient gold-catalyzed hydroarylation of alkynes under soft reaction conditions is developed by utilizing a bifunctional ligand. This transformation features a broad substrate scope and thus exhibits moderate to excellent efficiency.

引用

页码：6045 / 6049

页数：5

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