Oxidative Coupling of Methane: Optimal Operating Policies for a Membrane Reactor Network

被引:4
|
作者
Lenhart, Eva [1 ]
Esche, Erik [1 ]
Arellano-Garcia, Harvey [1 ]
Biegler, Lorenz T. [2 ]
机构
[1] Tech Univ Berlin, Fachgebiet Dynam & Betrieb Tech Anlagen, D-10623 Berlin, Germany
[2] Carnegie Mellon Univ, Dept Chem Engn, Pittsburgh, PA 15213 USA
关键词
Membrane reactor network; Oxidative coupling of methane; Packed-bed membrane reactor; Process optimization; LA2O3/CAO CATALYST;
D O I
10.1002/cite.201200073
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The oxidative coupling of methane (OCM), in which methane is turned into ethylene and ethane, presents an opportunity for using natural gas to produce desired C2 hydrocarbons. The main challenge for the successful implementation of the process is the reduction of undesired by-products, such as CO2. This contribution deals with the optimization of a membrane reactor network for the OCM process with the goal of maximizing yield while maintaining simultaneously a high selectivity in C2 products. The network consists of a plug flow/fixed-bed reactor, a conventional packed-bed membrane reactor and a so-called proposed packed-bed membrane reactor.
引用
收藏
页码:1980 / 1988
页数:9
相关论文
共 50 条
  • [11] Using a membrane reactor for the oxidative coupling of methane: simulation and optimization
    Yaneeporn Patcharavorachot
    Sirikarn Tiraset
    Wisitsree Wiyaratn
    Suttichai Assabumrungrat
    Amornchai Arpornwichanop
    Clean Technologies and Environmental Policy, 2014, 16 : 1295 - 1306
  • [12] Design of a packed bed membrane reactor for the oxidative coupling of methane
    Chaudhari, A. S.
    Ramakers, J. J. F. E.
    Gallucci, F.
    Annaland, M. van Sint
    EUROMEMBRANE CONFERENCE 2012, 2012, 44 : 1724 - 1724
  • [13] Using a membrane reactor for the oxidative coupling of methane: simulation and optimization
    Patcharavorachot, Yaneeporn
    Tiraset, Sirikarn
    Wiyaratn, Wisitsree
    Assabumrungrat, Suttichai
    Arpornwichanop, Amornchai
    CLEAN TECHNOLOGIES AND ENVIRONMENTAL POLICY, 2014, 16 (07) : 1295 - 1306
  • [14] Oxidative coupling of methane in a catalytic bed reactor and a membrane reactor: Modeling and simulation
    Tye, CT
    Mohamed, AR
    Bhatia, S
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2004, 10 (05) : 834 - 844
  • [15] Model-Based Analysis of Reactor Feeding Policies for Methane Oxidative Coupling
    Godini, H. R.
    Arellano-Garcia, H.
    Omidkhah, M.
    Karimzadeh, R.
    Wozny, G.
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2010, 49 (08) : 3544 - 3552
  • [16] Oxidative coupling of methane in a perovskite hollow-fiber membrane reactor
    Tan, XY
    Li, K
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (01) : 142 - 149
  • [17] OXIDATIVE COUPLING OF METHANE IN A MIXED-CONDUCTING PEROVSKITE MEMBRANE REACTOR
    TENELSHOF, JE
    BOUWMEESTER, HJM
    VERWEIJ, H
    APPLIED CATALYSIS A-GENERAL, 1995, 130 (02) : 195 - 212
  • [18] Oxidative Coupling of Methane in a BCFZ Perovskite Hollow Fiber Membrane Reactor
    Czuprat, Oliver
    Schiestel, Thomas
    Voss, Hartwig
    Caro, Juergen
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2010, 49 (21) : 10230 - 10236
  • [19] Multiobjective Optimization of a Porous Ceramic Membrane Reactor for Oxidative Coupling of Methane
    Quddus, Mohammad R.
    Zhang, Yan
    Ray, Ajay K.
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2010, 49 (14) : 6469 - 6481
  • [20] Oxygen-permeable dense membrane reactor for the oxidative coupling of methane
    Lu, YP
    Dixon, AG
    Moser, WR
    Ma, YH
    Balachandran, U
    JOURNAL OF MEMBRANE SCIENCE, 2000, 170 (01) : 27 - 34