Palladium nanoparticles stabilized by sterically hindered phosphonium salts as Suzuki cross-coupling catalysts

被引：16

作者：

Ermolaev, V. V. ^{[1
]}

Arkhipova, D. M. ^{[1
]}

Nigmatullina, L. Sh. ^{[1
]}

Rizvanov, I. Kh. ^{[1
]}

Milyukov, V. A. ^{[1
]}

Sinyashin, O. G. ^{[1
]}

机构：

[1] Russian Acad Sci, Kazan Res Ctr, AE Arbuzov Organ & Phys Chem Inst, Kazan 420088, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2013年 / 62卷 / 03期

关键词：

palladium nanoparticles; bromoarenes; catalysis; cross-coupling; arylboronic acids; IONIC LIQUIDS; PD NANOPARTICLES; EFFICIENT CATALYSTS; ARYL HALIDES; SOLVENTS;

D O I：

10.1007/s11172-013-0088-z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Palladium nanoparticles with an average size of 2.5 +/- 0.5 nm formed from palladium acetate in the presence of tri-tert-butyl(decyl)phosphonium tetrafluoroborate without an additional reducing agent exhibit high activity as a catalyst for the Suzuki cross-coupling reaction involving bromo- and chloroarenes under mild conditions.

引用

页码：657 / 660

页数：4

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