Synthesis and characterisation of tetramethylfulvene complexes of ruthenium

被引：7

作者：

Rodriguez-Barzano, Andrea ^{[1
]}

Blacker, A. John ^{[1
]}

McGowan, Patrick C. ^{[1
]}

机构：

[1] Univ Leeds, Sch Chem, IPRD, Leeds LS2 9JT, W Yorkshire, England

来源：

DALTON TRANSACTIONS | 2013年 / 42卷 / 48期

基金：

英国工程与自然科学研究理事会;

关键词：

C-H ACTIVATION; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURES; THERMOLYSIS; LIGAND; RU; DEPROTONATION; DIOXYGEN; IRIDIUM; BONDS;

D O I：

10.1039/c3dt52747f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of [RuCp*Cl-2](2) with dibenzoylmethane and triethylamine, in either dichloromethane or toluene, produced the complexes [RuCl(eta(6)-C5Me4CH2)(PhCOCCOPh)] (1) and [RuCl3(eta(6)-C5Me4CH2)][RuCp*(C6H5CH3)] (2) respectively under mild conditions. Both compounds 1 and 2 are examples of an unusual tetramethylfulvene-ruthenium structure, obtained by deprotonation of the pentamethylcyclopentadienyl ligand, and were characterised by single-crystal X-ray diffraction.

引用

页码：16669 / 16671

页数：3

共 21 条

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