Synthesis and characterisation of tetramethylfulvene complexes of ruthenium

被引：7
作者：
Rodriguez-Barzano, Andrea [1 ]
Blacker, A. John [1 ]
McGowan, Patrick C. [1 ]
机构：
[1] Univ Leeds, Sch Chem, IPRD, Leeds LS2 9JT, W Yorkshire, England
来源：
DALTON TRANSACTIONS | 2013年 / 42卷 / 48期
基金：
英国工程与自然科学研究理事会;
关键词：
C-H ACTIVATION; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURES; THERMOLYSIS; LIGAND; RU; DEPROTONATION; DIOXYGEN; IRIDIUM; BONDS;
D O I：
10.1039/c3dt52747f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions of [RuCp*Cl-2](2) with dibenzoylmethane and triethylamine, in either dichloromethane or toluene, produced the complexes [RuCl(eta(6)-C5Me4CH2)(PhCOCCOPh)] (1) and [RuCl3(eta(6)-C5Me4CH2)][RuCp*(C6H5CH3)] (2) respectively under mild conditions. Both compounds 1 and 2 are examples of an unusual tetramethylfulvene-ruthenium structure, obtained by deprotonation of the pentamethylcyclopentadienyl ligand, and were characterised by single-crystal X-ray diffraction.
引用
收藏
页码：16669 / 16671
页数：3
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