NIR-Sensitive Poly(3,4-ethylenedioxyselenophene) Derivatives for Transparent Photo-Thermo-Electric Converters

被引：125
作者：
Kim, Byeonggwan [1 ]
Shin, Haijin [1 ]
Park, Teahoon [1 ]
Lim, Hanwhuy [1 ]
Kim, Eunkyoung [1 ]
机构：
[1] Yonsei Univ, Dept Chem & Biomol Engn, Act Polymer Ctr Pattern Integrat, Seoul 120749, South Korea
来源：
ADVANCED MATERIALS | 2013年 / 25卷 / 38期
基金：
新加坡国家研究基金会;
关键词：
conductive polymer; polyselenophene; electrochromic material; near-infrared absorption; night vision; NIR conversion into electricity; REDUCED GRAPHENE OXIDE; PHOTOTHERMAL ABLATION; ELECTROCHROMIC PROPERTIES; CONVERSION EFFICIENCY; THIN-FILM; POLYMERS; NANOPARTICLES; NANOCRYSTALS; NANORODS; ENERGY;
D O I：
10.1002/adma.201301834
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Electrochromism, photothermal effect, and thermoelectric properties of hexyl-derivatized poly(3,4-ethylenedioxyselenophene) are investigated by precisely controlling the morphology. These properties are clearly demonstrated by controlling the applied electrical potential of the polymer films. Especially, the doped polymer film at -0.1 V reveals the highest photothermal conversion efficiency and a power factor of 42.5% and 354.7 μW m-1 K-2, respectively. Efficient visible to near-infrared absorption, photon to heat, and heat to electric conversion has been realized in one film that could benefit in exploiting multifunctional film displays, invisible NIR sensors, photodynamic theragnosis, and thermoelectric devices. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：5483 / 5489
页数：7
相关论文
共 47 条
  • [1] Iodine doped polyaniline thin film for heterostructure devices via PECVD technique: Morphological, structural, and electrical properties
    Ameen, Sadia
    Song, Minwu
    Kim, Don-Gyu
    Im, Yu-Bin
    Seo, Hyung-Kee
    Kim, Young Soon
    Shin, Hyung-Shik
    [J]. MACROMOLECULAR RESEARCH, 2012, 20 (01) : 30 - 36
  • [2] Forming nanomaterials as layered functional structures toward materials nanoarchitectonics
    Ariga, Katsuhiko
    Ji, Qingmin
    Hill, Jonathan P.
    Bando, Yoshio
    Aono, Masakazu
    [J]. NPG ASIA MATERIALS, 2012, 4 : e17 - e17
  • [3] Color Control in π-Conjugated Organic Polymers for Use in Electrochromic Devices
    Beaujuge, Pierre M.
    Reynolds, John R.
    [J]. CHEMICAL REVIEWS, 2010, 110 (01) : 268 - 320
  • [4] Reversible Full-Color Generation with Patterned Yellow Electrochromic Polymers
    Bhuvana, Thiruvelu
    Kim, Byeonggwan
    Yang, Xu
    Shin, Haijin
    Kim, Eunkyoung
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (04) : 1180 - 1184
  • [5] Electroactive subwavelength gratings (ESWGs) from conjugated polymers for color and intensity modulation
    Bhuvana, Thiruvelu
    Kim, Byeonggwan
    Yang, Xu
    Shin, Haijin
    Kim, Eunkyoung
    [J]. NANOSCALE, 2012, 4 (12) : 3679 - 3686
  • [6] Bubnova O, 2011, NAT MATER, V10, P429, DOI [10.1038/NMAT3012, 10.1038/nmat3012]
  • [7] Far infrared electrochromism in unique conducting polymer systems
    Chandrasekhar, P
    Birur, GC
    Stevens, P
    Rawal, S
    Pierson, EA
    Miller, KL
    [J]. SYNTHETIC METALS, 2001, 119 (1-3) : 293 - 294
  • [8] Effects of insert film on asymmetric mold temperature and associated part warpage during in-mold decoration injection molding of PP parts
    Chen, Hui-Li
    Chen, Shia-Chung
    Liao, Won-Hsion
    Chien, Rean-Der
    Lin, Yu-Tseng
    [J]. INTERNATIONAL COMMUNICATIONS IN HEAT AND MASS TRANSFER, 2013, 41 : 34 - 40
  • [9] The therapeutic efficacy of CdTe and CdSe quantum dots for photothermal cancer therapy
    Chu, Maoquan
    Pan, Xiaojing
    Zhang, Ding
    Wu, Qiang
    Peng, Jinliang
    Hai, Wangxi
    [J]. BIOMATERIALS, 2012, 33 (29) : 7071 - 7083
  • [10] 서석재, 2013, [Journal of Korean Society for Imaging Science and Technology, 한국화상학회지], V19, P25
12345