Truxillic and truxinic acid-based, bio-derived diesters as potent internal donor in Ziegler-Natta catalyst for propylene polymerization

被引:20
作者
Matta, Akanksha [1 ]
Chammingkwan, Patchanee [1 ]
Singh, Brajendra K. [2 ]
Terano, Minoru [1 ]
Kaneko, Tatsuo [1 ]
Taniike, Toshiaki [1 ]
机构
[1] Japan Adv Inst Sci & Technol, Grad Sch Adv Sci & Technol, 1-1 Asahidai, Nomi, Ishikawa 9231292, Japan
[2] Univ Delhi, Dept Chem, Bioorgan Lab, Delhi 110007, India
关键词
Bio-derived diester; Internal donor; Ziegler-Natta catalyst; Propylene polymerization; Hydrogen response; Density functional calculation; ELECTRON-DONORS; CINNAMIC ACID; PSEUDOPOTENTIALS; ELEMENTS; SUPPORT; TICL4;
D O I
10.1016/j.apcata.2018.01.030
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study, novel alpha-truxillic and beta-truxinic acid-based, bio-derived diesters have been developed as internal donors for preparing Ziegler-Natta (ZN) catalysts. Impacts of these bio-derived diesters were investigated on the chemical composition, the morphology, the mode of adsorption, and the propylene polymerization performance of the catalysts in comparison to the most widely used fourth-generation catalyst containing dibutyl phthalate. The molecular structures of the diesters and the particle morphology of the catalysts were preserved in the catalyst preparation. The bio-derived diesters afforded ZN catalysts with a reasonable activity and stereo specificity in propylene polymerization along with similarly broad molecular weight distribution (MWD) as the phthalate-based catalyst. Another promising feature of the catalysts was an opposite hydrogen response in terms of expansion of MWD upon the addition of H-2.
引用
收藏
页码:80 / 87
页数:8
相关论文
共 43 条
[1]  
Albizzati E., 1990, Patent No. [EP361,494A1, 361494]
[2]  
BAI Y, 1975, J BIOCHEM-TOKYO, V77, P81
[3]  
Baranowska M. K., 2002, ACTA POL PHARM, V59, P403
[4]   AB-INITIO ENERGY-ADJUSTED PSEUDOPOTENTIALS FOR ELEMENTS OF GROUPS 13-17 [J].
BERGNER, A ;
DOLG, M ;
KUCHLE, W ;
STOLL, H ;
PREUSS, H .
MOLECULAR PHYSICS, 1993, 80 (06) :1431-1441
[5]   The photochemical dimerization of trans-cinnamic acid [J].
Bernstein, HI ;
Quimby, WC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1943, 65 :1845-1846
[6]   High-Throughput Synthesis of Support Materials for Olefin Polymerization Catalyst [J].
Chammingkwan, Patchanee ;
Terano, Minoru ;
Taniike, Toshiaki .
ACS COMBINATORIAL SCIENCE, 2017, 19 (05) :331-342
[7]   Antinociceptive activities of α-truxillic acid and β-truxinic acid derivatives [J].
Chi, YM ;
Nakamura, M ;
Zhao, XY ;
Yoshizawa, T ;
Yan, WM ;
Hashimoto, F ;
Kinjo, J ;
Nohara, T ;
Sakurada, S .
BIOLOGICAL & PHARMACEUTICAL BULLETIN, 2006, 29 (03) :580-584
[8]   Anti-inflammatory activities of α-truxillic acid derivatives and their monomer components [J].
Chi, YM ;
Nakamura, M ;
Yoshizawa, T ;
Zhao, XY ;
Yan, WM ;
Hashimoto, F ;
Kinjo, J ;
Nohara, T ;
Sakurada, S .
BIOLOGICAL & PHARMACEUTICAL BULLETIN, 2005, 28 (09) :1776-1778
[9]  
Chumachenko N.N., 2017, Polyolef. J., V4, P111
[10]   Key elements in the structure and function relationship of the MgCl2/TiCl4/Lewis base Ziegler-Natta catalytic system [J].
Correa, Andrea ;
Piemontesi, Fabrizio ;
Morini, Giampiero ;
Cavallo, Luigi .
MACROMOLECULES, 2007, 40 (25) :9181-9189