Cis- and Trans-Coordination Assembly of Nitrogen Heterocycle with Copper(II) and Silver(I)

被引：0

作者：

Tan Di ^{[2
]}

Tan Gui-ping ^{[2
]}

Huang Xiao-chun ^{[2
]}

Tong Shan-ling ^{[1
,2
]}

Yang Ke-er ^{[2
]}

Yan Yan ^{[1
,2
]}

机构：

[1] Guangdong Univ Technol, Dept Light Ind & Chem Engn, Guangzhou 510006, Guangdong, Peoples R China

[2] Shantou Univ, Dept Chem, Shantou 515063, Peoples R China

来源：

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 2008年 / 24卷 / 06期

基金：

中国国家自然科学基金;

关键词：

Nitrogen heterocycle; Cis- and trans-coordination; Copper; Silver;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

After the preparation of 1,4-bis(4.5-dihydro-1H-imidazol-2-yl)benzene(bdib), a nitrogen heterocycle with potential coordination manners of both cis- and trans-configuration forms, three complexes, including cis-[Cu-2(bdib)(2)(mu-OCH3)(2)]Cl(2)(.)2MeOH(1), trans-[Cu(bdib)(AcO)(2)](n)(2), and cis-[Ag-2(bdib)(2)](NO3)(2)(.)2H(2)O(3), were successfully self-assembled. Complexes I and 2 crystallized in the monoclinic system with P2(1)/(n) space group and complex 3 in the triclinic system with P (1) over bar space group.

引用

页码：661 / 667

页数：7

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