2,2′-Bipyridyl as a Redox-Active Borylene Abstraction Agent

被引：7

作者：

Liu, Siyuan ^{[1
,2
]}

Legare, Marc-Andre ^{[1
,2
]}

Seufert, Jens ^{[1
,2
]}

Prieschl, Dominic ^{[1
,2
]}

Rempel, Anna ^{[1
,2
]}

Englert, Lukas ^{[1
,2
]}

Dellermann, Theresa ^{[1
,2
]}

Paprocki, Valerie ^{[1
,2
]}

Stoy, Andreas ^{[1
,2
]}

Braunschweig, Holger ^{[1
,2
]}

机构：

[1] Julius Maximilians Univ Wurzburg, Inst Inorgan Chem, D-97074 Wurzburg, Germany

[2] Julius Maximilians Univ Wurzburg, Inst Sustainable Chem & Catalysis Boron, D-97074 Wurzburg, Germany

来源：

INORGANIC CHEMISTRY | 2020年 / 59卷 / 15期

基金：

欧洲研究理事会;

关键词：

INTRAMOLECULAR STERIC INTERACTIONS; NUCLEOPHILE CARBEN-CHEMIE; SILICON-COMPOUNDS; BORON; REACTIVITY; BOND; COMPLEXES; COORDINATION; GENERATION; DIBORATION;

D O I：

10.1021/acs.inorgchem.0c01383

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

2,2'-Bipyridyl is shown to spontaneously abstract a borylene fragment (R-B:) from various hypovalent boron compounds. This process is a redox reaction in which the bipyridine is reduced and becomes a dianionic substituent bound to boron through its two nitrogen atoms. Various transition metal-borylene complexes and diboranes, as a well as a diborene, take part in this reaction. In the latter case, our results show an intriguing example of the homolytic cleavage of a B=B double bond.

引用

页码：10866 / 10873

页数：8

共 50 条

[31] Crystal Structure of cis-Bis(2,2′-bipyridyl)bis(trifluoromethanesulfonato)cobalt(II)
Toyama, Mari
Yamamoto, Yu
X-RAY STRUCTURE ANALYSIS ONLINE, 2019, 35 : 21 - 23
[32] Synthesis and Characterization of Dioxomolybdenum(VI) Complexes with 1,10-Phenanthroline and 2,2′-Bipyridyl
Khojasteh, R. R.
Saremi, Sajedeh Lotfalian
Ahmadzadeh, M.
ASIAN JOURNAL OF CHEMISTRY, 2011, 23 (08) : 3769 - 3770
[33] Structure of bis(2-Thiobarbiturate)Tris (2,2-Bipyridyl)Nickel(II) Hexahydrate
Golovnev, N. N.
Molokeev, M. S.
Sterkhova, I. V.
Lesnikov, M. K.
Samoilo, A. S.
JOURNAL OF STRUCTURAL CHEMISTRY, 2019, 60 (01) : 111 - 116
[34] Insights into the Chemistry and Structural Features of the Copper(ii) 2,2′-Bipyridyl-Thiosulfate System
Ainscough, Eric W.
Woodhouse, Sidney S.
Brodie, Andrew M.
Freeman, Graham H.
Plieger, Paul G.
AUSTRALIAN JOURNAL OF CHEMISTRY, 2020, 73 (01) : 43 - 48
[35] Analysis of Lanthanide-Radical Magnetic Interactions in Ce(III) 2,2'-Bipyridyl Complexes
Ortu, Fabrizio
Liu, Jingjing
Burton, Matthew
Fowler, Jonathan M.
Formanuik, Alasdair
Boulon, Marie-Emmanuelle
Chilton, Nicholas F.
Mills, David P.
INORGANIC CHEMISTRY, 2017, 56 (05) : 2496 - 2505
[36] Soluble Redox-Active Polymetallic Chains [{Ru0(CO)(L)(bpy)}m]n (bpy=2,2′-bipyridine, L = PrCN, Cl-; m=0,-1): Electrosynthesis and Characterization
Hartl, Frantisek
Renfrew, Anna K.
Lafolet, Frederic
Mahabiersing, Taasje
Calhorda, Maria Jose
Chardon-Noblat, Sylvie
Haukka, Matti
Deronzier, Alain
INORGANIC CHEMISTRY, 2009, 48 (17) : 8233 - 8244
[37] Ru(II) Complexes with a Chemical and Redox-Active S2N2 Ligand: Structures, Electrochemistry, and Metal-Ligand Cooperativity
Durgaprasad, Gummadi
Luna, Javier A.
Spielvogel, Kyle D.
Haas, Christian
Shaw, Scott K.
Daly, Scott R.
ORGANOMETALLICS, 2017, 36 (20) : 4020 - 4031
[38] Boron Cluster Anions [B10X10]2- (X = H, Cl) in Manganese(II) Complexation with 2,2'-Bipyridyl
Avdeeva, V. V.
Vologzhanina, A. V.
Malinina, E. A.
Zhizhin, K. Yu
Kuznetsov, N. T.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2019, 45 (04) : 295 - 300
[39] Comparisons of MN2S2 vs. bipyridine as redox-active ligands to manganese and rhenium in (L-L)M'(CO)3Cl complexes
Lunsford, Allen M.
Goldstein, Kristina F.
Cohan, Matthew A.
Denny, Jason A.
Bhuvanesh, Nattamai
Ding, Shengda
Hall, Michael B.
Darensbourg, Marcetta Y.
DALTON TRANSACTIONS, 2017, 46 (16) : 5175 - 5182
[40] N2,N2′-Bis(2-hydroxybenzylidene)-2,2′-bipyridyl-3,3′-dicarbohydrazide
Miao, Shao-Bin
Zang, Lu-Lu
Fan, Ya-Wei
Ji, Bao-Ming
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O75 - U1921

← 1 2 3 4 5 →