Co(II) or Cu(II) Schiff Base Complex Immobilized onto Carbon Nanotubes as a Synergistic Catalyst for the Oxygen Reduction Reaction

被引：12

作者：

Bai, Lu ^{[1
]}

Li, Min ^{[1
]}

Guan, Jingqi ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, Changchun 130023, Jilin, Peoples R China

来源：

CHEMISTRYSELECT | 2018年 / 3卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Cobalt complex; Copper complex reaction; Oxygen reduction; Schiff base; NITROGEN-DOPED CARBON; HIGHLY EFFICIENT CATALYST; ELECTROCATALYST; OXIDATION; ALKALINE; IRON; ELECTROCHEMISTRY; NANOPARTICLES; BATTERIES; STYRENE;

D O I：

10.1002/slct.201702801

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Heterogenization of molecular catalysts not only showed excellent activity and selectivity in many catalytic reactions, but also provided definite active sites feasible to explore the reaction mechanism. Herein, we report a heterogenization of metal Schiff-base complex immobilized on multiwalled carbon nanotubes (MWCNTs) as a high-performance catalyst for the oxygen reduction reaction (ORR). Although MWCNTs alone have little catalytic activity, the heterogenization hybrid exhibits an enhanced ORR activity in alkaline solutions. The enhanced catalytic activity arises from synergetic effects between metal Schiff-base complexes and MWCNTs.

引用

页码：581 / 585

页数：5

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