Selective hydroxylation of cyclic ethers with tert-butylhydroperoxide and hydrogen peroxide catalyzed by iron(III) and manganese(II) bipyridine complexes included in zeolite Y and bentonite

被引：23

作者：

Salavati-Niasari, M

Farzaneh, F ^{[1
]}

Ghandi, M

机构：

[1] Univ Az Zahra, Dept Chem, Tehran, Iran

[2] Univ Tehran, Dept Chem, Tehran, Iran

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2001年 / 175卷 / 1-2期

关键词：

hydroxylation; cyclic ethers; zeolite Y; bentonite;

D O I：

10.1016/S1381-1169(01)00101-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The oxidation of cyclic ethers such as tetrahydrofuran (THF), tetrahydropyran (THP), 2,3-dihydropyran (DHP) and 1,4-dioxan (DO), with hydrogen peroxide (H2O2) and tert-butylhydroperoxide (TBHP) in the presence of iron(III) and manganese(II) bipyridine complexes included in zeolite Y and bentonite are described. The products are mainly cyclic ether-2-ols and cyclic ether-2-ones with minor amounts of 2,3-dihydrocyclic ether. (C) 2001 Elsevier Science B.V. All rights reserved.

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页码：105 / 110

页数：6

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