Curing of a phenol-formaldehyde-tannin adhesive in the presence of wood -: Analysis by differential scanning calorimetry

被引:19
|
作者
Vazquez, G. [1 ]
Gonzalez-Alvarez, J. [1 ]
Antorrena, G. [1 ]
机构
[1] Univ Santiago de Compostela, Sch Engn, Dept Chem Engn, Santiago De Compostela 15782, Spain
关键词
activation energy; adhesive; wood interaction; curing enthalpy; DSC; phenol-formaldehyde-tannin adhesive;
D O I
10.1007/s10973-005-9989-x
中图分类号
O414.1 [热力学];
学科分类号
摘要
The curing of a phenol-formaldehyde-tannin (PFT) adhesive in the presence of pine or eucalyptus wood has been studied using differential scanning calorimetry. The influence of the adhesive/wood ratio on the activation energy (E-a), the temperature of the maximum of the exothermic peak (T-p) and the enthalpy of the curing process (Delta H) was analysed. E-a, T-p and Delta H of the curing reaction decreased when wood was added in the curing system. The adhesive/wood interaction did not depend significantly on wood species.
引用
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页码:651 / 654
页数:4
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