Palladium-Catalyzed Direct Arylation of Polyfluoroarenes with Organosilicon Reagents

被引：12
|
作者：
Fan, Huixin [1 ]
Shang, Yaping [1 ]
Su, Weiping [1 ]
机构：
[1] Chinese Acad Sci Yangqiao West, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 2014卷 / 16期
基金：
中国国家自然科学基金;
关键词：
C-H activation; Cross-coupling; Palladium; Biaryls; Arenes; Silicon; Fluorine; CROSS-COUPLING REACTIONS; H BOND ARYLATION; ELECTRON-DEFICIENT POLYFLUOROARENES; C-H; ROOM-TEMPERATURE; ARYLBORONIC ACIDS; ALKYL BROMIDES; ARYL BROMIDES; N-OXIDES; SILICON;
D O I：
10.1002/ejoc.201402091
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The palladium-catalyzed direct arylation of polyfluoroarenes with organosilicon reagents was achieved by establishing general reaction conditions. This protocol was compatible with a broad range of functional groups and offered the desired products in moderate to good yields.
引用
收藏
页码：3323 / 3327
页数：5
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