Aqueous room temperature metal-catalyzed living radical polymerization of vinyl chloride

被引：399

作者：

Percec, V ^{[1
]}

Popov, AV ^{[1
]}

Ramirez-Castillo, E ^{[1
]}

Monteiro, M ^{[1
]}

Barboiu, B ^{[1
]}

Weichold, O ^{[1
]}

Asandei, AD ^{[1
]}

Mitchell, CM ^{[1
]}

机构：

[1] Univ Penn, Dept Chem, Roy & Diana Vagelos Labs, Philadelphia, PA 19104 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 18期

关键词：

D O I：

10.1021/ja0256055

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper describes the room-temperature living radical polymerization (LRP) of vinyl chloride in H2O/THF in the presence of Cu0 or CuI salts as catalysts, tren or PEI as ligands, and iodoform as initiator. The disproportionation reaction 2CuI + L → Cu0 + CuII(L) is the crucial step, as it continuously provides the active species for both the initiation (Cu0) and the reversible termination step (CuII). Mn was found to increase linearly with conversion and is in good agreement with Mth, with the Mw/Mn being approximately 1.5. Copyright © 2002 American Chemical Society.

引用

页码：4940 / 4941

页数：2

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