Non-stoichiometry in "CaCu3Ti4O12" (CCTO) ceramics

被引：103
|
作者：
Schmidt, Rainer [1 ]
Pandey, Shubhra [2 ,3 ]
Fiorenza, Patrick [4 ]
Sinclair, Derek C. [2 ]
机构：
[1] Univ Complutense Madrid, Fac Ciencias Fis, Dept Fis Aplicada 3, GFMC, E-28040 Madrid, Spain
[2] Univ Sheffield, Sheffield S1 3JD, S Yorkshire, England
[3] Indian Inst Technol, Dept Mat Sci & Engn, Kanpur 208016, Uttar Pradesh, India
[4] CNR, IMM, I-95121 Catania, Italy
来源：
RSC ADVANCES | 2013年 / 3卷 / 34期
基金：
英国工程与自然科学研究理事会;
关键词：
GIANT DIELECTRIC-CONSTANT; EFFECTIVE IONIC-RADII; OXIDES;
D O I：
10.1039/c3ra41319e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A combined powder X-ray lattice parameter and ceramic impedance spectroscopy study is presented on materials within the CaO-CuO-TiO2 ternary phase diagram. Several compositions containing CaCu3Ti4O12 (CCTO) and small amounts of secondary phases such as TiO2, CaTiO3 and CuO are analysed and two different defect mechanisms are identified as the cause of the non-stoichiometry in CCTO. The first mechanism involves a variation in the Cu content, which explains the large differences in the intrinsic bulk and extrinsic grain boundary (GB) resistance, and the formation of the ceramic internal barrier layer capacitor (IBLC) structure. The second mechanism is associated with Ca-Cu anti-site disorder causing an unusually high intrinsic bulk permittivity above that predicted from Clausius-Mossotti calculations.
引用
收藏
页码：14580 / 14589
页数：10
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