Seeds obtained from a hydrated polymorph permit crystallisation of an elusive anhydrous organometallic zwitterion

被引：32

作者：

Braga, D

Cojazzi, G

Maini, L

Polito, M

Grepioni, F

机构：

[1] Univ Bologna, Dipartimento Chim G Ciamician, CNR, Ctr Fis Macromol, I-40126 Bologna, Italy

[2] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 19期

关键词：

D O I：

10.1039/a904951g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single crystals of the anhydrous polymorphic modification of the organometallic zwitterion [Co-III(eta(5)-C5H4CO2H)(eta(5)-C5H4CO2)] can only be obtained by seeding the solution with seeds prepared after stepwise dehydration and consequent phase transition at 506 K of the hydrated material [Co-III(eta(5)-C5H4CO2H)(eta(5)-C5H4CO2)]. 3H(2)O.

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页码：1949 / 1950

页数：2

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