Ir-Catalyzed enantioselective group transfer reactions

被引：24

作者：

Schafer, Andrew G. ^{[1
]}

Blakey, Simon B. ^{[1
]}

机构：

[1] Emory Univ, Dept Chem, Atlanta, GA 30322 USA

来源：

CHEMICAL SOCIETY REVIEWS | 2015年 / 44卷 / 17期

基金：

美国国家科学基金会;

关键词：

ALKYL-ALPHA-DIAZOESTERS; C-H INSERTION; CO(II)-BASED METALLORADICAL CATALYSIS; CHIRAL IRIDIUM(III) COMPLEX; CARBENE INSERTION; ORGANIC-SYNTHESIS; PORPHYRIN LIGAND; CYCLOPROPANATION; CYCLOPROPENATION; CONSTRUCTION;

D O I：

10.1039/c5cs00354g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recently, several novel iridium complexes have been shown to catalyse group transfer reactions in a highly selective fashion. Rhodium complexes, and in particular dirhodium tetracarboxylate salts, have proven to be a remarkably useful class of catalysts for these reactions through several decades of development. Recent results suggest that iridium may offer opportunities to address challenges in this chemistry and provide complementary reactivity patterns. This tutorial review outlines the recent developments in Ir-catalyzed enantioselective group transfer chemistry with highlights on examples which display this unique reactivity.

引用

页码：5969 / 5980

页数：12

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