gas chromatography;
packed column;
alumina;
fluorinated polyimide ( PI) modifier;
inorganic and organic gases;
hydrocarbons;
D O I:
10.1134/S1061934813100110
中图分类号:
O65 [分析化学];
学科分类号:
070302 ;
081704 ;
摘要:
Highly fluorinated thermally stable polyimide is synthesized and used to modify alumina. The effects of polyimide concentration (10 and 15 wt %) and thermal treatment conditions on the adsorption and chromatographic properties of the prepared adsorbents are studied by the low-temperature adsorption of nitrogen and gas chromatography on packed columns. The adsorbents prepared possess mesoporous structures and ensure the selective separation of permanent gases and hydrocarbons on their simultaneous presence.