A new 3D Cu(I) coordination polymer with 4-connected umv topological network

被引：6
|
作者：
Shang, Jie [1 ,2 ]
Wu, Xiao-Yuan [1 ]
Wang, Fei [1 ]
Yang, Wen-Bin [1 ]
Yu, Rong-Min [1 ]
Lu, Can-Zhong [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 35002, Fujian, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 22卷
基金：
中国国家自然科学基金;
关键词：
Copper; Hydrothermal synthesis; Topology; Luminescence; MOFs; METAL-ORGANIC FRAMEWORKS; UNSYMMETRIC LIGAND; ZN-II; COMPLEXES; LUMINESCENCE;
D O I：
10.1016/j.inoche.2012.05.042
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Here we synthesize a novel 3D luminescent Cu-I-coordination polymer. X-ray structure analysis revealed that 1 is constructed from both left- and right-handed copper-sulfur helical chains combined by pyt-ligands into a 3D 4-connected framework with the (4(2) . 6(3) . 8) umv topology. Upon photo excitation, 1 exhibits strong green light-emission in solid state at room temperature. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：190 / 192
页数：3
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