A new 3D Cu(I) coordination polymer with 4-connected umv topological network

被引：6

作者：

Shang, Jie ^{[1
,2
]}

Wu, Xiao-Yuan ^{[1
]}

Wang, Fei ^{[1
]}

Yang, Wen-Bin ^{[1
]}

Yu, Rong-Min ^{[1
]}

Lu, Can-Zhong ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 35002, Fujian, Peoples R China

[2] Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 22卷

基金：

中国国家自然科学基金;

关键词：

Copper; Hydrothermal synthesis; Topology; Luminescence; MOFs; METAL-ORGANIC FRAMEWORKS; UNSYMMETRIC LIGAND; ZN-II; COMPLEXES; LUMINESCENCE;

D O I：

10.1016/j.inoche.2012.05.042

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Here we synthesize a novel 3D luminescent Cu-I-coordination polymer. X-ray structure analysis revealed that 1 is constructed from both left- and right-handed copper-sulfur helical chains combined by pyt-ligands into a 3D 4-connected framework with the (4(2) . 6(3) . 8) umv topology. Upon photo excitation, 1 exhibits strong green light-emission in solid state at room temperature. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：190 / 192

页数：3

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