AgCu3V4O12: a Novel Perovskite Containing Mixed-Valence Silver ions

被引：7
|
作者：
Akizuki, Yasuhide [1 ]
Yamada, Ikuya [2 ,3 ]
Fujita, Koji [1 ]
Akamatsu, Hirofumi [4 ,5 ]
Irifune, Tetsuo [6 ]
Tanaka, Katsuhisa [1 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Mat Chem, Nishikyo Ku, Kyoto 6158510, Japan
[2] Osaka Prefecture Univ, Nanosci & Nanotechnol Res Ctr, Naka Ku, Sakai, Osaka 5998531, Japan
[3] JST PRESTO, Kawaguchi, Saitama 3320012, Japan
[4] Penn State Univ, Mat Res Inst, University Pk, PA 16802 USA
[5] Penn State Univ, Dept Mat Sci & Engn, University Pk, PA 16802 USA
[6] Ehime Univ, Geodynam Res Ctr, Matsuyama, Ehime 7908577, Japan
来源：
INORGANIC CHEMISTRY | 2013年 / 52卷 / 24期
关键词：
CRYSTAL-STRUCTURE; X-RAY; NEUTRON-DIFFRACTION; AGCUO2; NACUO2;
D O I：
10.1021/ic402579v
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel silver-containing perovskite, Ag-Cu3V4O12, was synthesized under high-pressure and high-temperature conditions. It crystallizes in an A-site-ordered perovskite structure (space group Im (3) over bar), in which silver ions occupy the 12-coordinated A sites forming regular icosahedra, and exhibits metallic behavior. Bond-valencesum calculations and X-ray photoemission spectroscopy reveal that Ag ions are present in the mixed-valence state, most likely attributable to the coexistence of Ag+ and Ag3+, unlike the case of well-known perovskite-type AgNbO3 and AgTaO3 containing only Ag+ ions. We discuss metallic conduction in relation to electronic structure calculations.
引用
收藏
页码：13824 / 13826
页数：3
相关论文
共 50 条
  • [31] Hydrothermal Syntheses and Crystal Structures of Two New Mixed-valence Vanadium Oxides [Ni(en)2(H2O)2][Ni(en)3]2[V16O38Cl]•3(H2O) and (H3O)2V3O8
    Liu, Xing
    Yin, Xian-Hong
    Zhang, Feng
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2010, 65 (12): : 1451 - 1456
  • [32] A Novel Mixed-valence and Capped-keggin Structural Polyoxometal Complex: {[Co(dien)]4-[(PO4)Mov 8(WVI0.56 MoVI0.44)4O33(OH)3]}•nH2O (n ≈ 1)
    Hu Zhi-Biao
    Chen Wu-Hua
    Mi Jin-Xiao
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2013, 32 (11) : 1653 - 1662
  • [33] Chemical Bond Characterization of a Mixed-Valence Tr-Cobalt Complex, Co3(μ-admtrz)4(μ-OH)2(CN)6•2H2O
    Wu, Lai-Chin
    Weng, Tsu-Chien
    Hsu, I-Jui
    Liu, Yi-Hung
    Lee, Gene-Hsiang
    Jyh-Fu, Lee
    Wang, Yu
    INORGANIC CHEMISTRY, 2013, 52 (19) : 11023 - 11033
  • [34] The crystal structures of the mixed-valence tellurium oxysalts tlapallite, (Ca,Pb)3CaCu6[Te34+Te6+O12]2(Te4+O3)2(SO4)2•3H2O, and carlfriesite, CaTe24+ Te6+O8
    Missen, Owen P.
    Kampf, Anthony R.
    Mills, Stuart J.
    Housley, Robert M.
    Spratt, John
    Welch, Mark D.
    Coolbaugh, Mark F.
    Marty, Joe
    Chorazewicz, Marek
    Ferraris, Cristiano
    MINERALOGICAL MAGAZINE, 2019, 83 (04) : 539 - 549
  • [35] Structure and Reactivity of the Mixed-Valence CaMn4O5(H2O)4 and CaMn4O4(OH)(H2O)4 Clusters at Oxygen Evolution Complex of Photosystem II. Hybrid DFT (UB3LYP and UBHandHLYP) Calculations
    Yamanaka, S.
    Saito, T.
    Kanda, K.
    Isobe, H.
    Umena, Y.
    Kawakami, K.
    Shen, J-R
    Kamiya, N.
    Okumura, M.
    Nakamura, H.
    Yamaguchi, K.
    INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 2012, 112 (01) : 321 - 343
  • [36] Novel rare earth activator ions-doped perovskite-type La4Ti3O12 phosphors: Facile synthesis, structure, multicolor emissions, and potential applications
    Wang, Guojing
    Jia, Guang
    Wang, Jianru
    Kong, Hanxiao
    Lu, Yaxian
    Zhang, Cuimiao
    JOURNAL OF ALLOYS AND COMPOUNDS, 2021, 877
  • [37] BLUESTREAKITE, K4Mg2(V24+V85+O28)•14H2O, A NEW MIXED-VALENCE DECAVANADATE MINERAL FROM THE BLUE STREAK MINE, MONTROSE COUNTY, COLORADO: CRYSTAL STRUCTURE AND DESCRIPTIVE MINERALOGY
    Kampf, Anthony R.
    Hughes, John M.
    Marty, Joe
    Nash, Barbara P.
    Chen, Yu-Sheng
    Steele, Ian M.
    CANADIAN MINERALOGIST, 2014, 52 (06) : 1007 - 1018
  • [38] VANARSITE, PACKRATITE, MORRISONITE, AND GATEWAYITE: FOUR NEW MINERALS CONTAINING THE [As3+V4+,5+12As5+6O51] HETEROPOLYANION, A NOVEL POLYOKOMETALATE CLUSTER
    Kampf, Anthony R.
    Hughes, John M.
    Nash, Barbara P.
    Marty, Joe
    CANADIAN MINERALOGIST, 2016, 54 (01) : 145 - 162
  • [39] Complex 5d Magnetism in a Novel S=1/2 Trimer System, the 12L Hexagonal Perovskite Ba4BiIr3O12
    Miiller, Wojciech
    Dunstan, Matthew T.
    Huang, Zixin
    Mohamed, Zakiah
    Kennedy, Brendan J.
    Avdeev, Maxim
    Ling, Chris D.
    INORGANIC CHEMISTRY, 2013, 52 (21) : 12461 - 12467
  • [40] SYNTHESIS METHOD AND CRYSTAL-STRUCTURE OF NOVEL MIXED-VALENCE MO-V-MO-VI POLYMETALLATE CLUSTER NA3H3[H8MO57FE(II)6O185(NO)(6)(H2O)(16)(MOO)(2)]CENTER-DOT-81H(2)O
    HUANG, GQ
    ZHANG, SW
    SHAO, MC
    CHINESE SCIENCE BULLETIN, 1995, 40 (17): : 1438 - 1441
12345