Preparation and properties of biodiesel from Cynara cardunculus L. oil

被引:125
作者
Encinar, JM [1 ]
González, JF [1 ]
Sabio, E [1 ]
Ramiro, MJ [1 ]
机构
[1] Univ Extremadura, Dept Ingn Quim & Energet, E-06071 Badajoz, Spain
关键词
D O I
10.1021/ie990012x
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A study was made of the reaction of transesterification of Cynara cardunculus L. oil by means of methanol, using sodium hydroxide, potassium hydroxide, and sodium methoxide as catalysts. The objective of the work was to characterize the methyl esters for use as biodiesels in internal combustion motors. The operation variables used were methanol concentration (5-21 wt %), catalyst concentration (0.1-1 wt %), and temperature (25-60 degrees C). The evolution of the process was followed by gas chromatography, determining the concentration of the methyl esters at different reaction times. The biodiesel was characterized by determining its density, viscosity, high heating value, cetane index, cloud and pour points, Ramsbottom carbon residue, characteristics of distillation, and flash and combustion points according to ISO norms. The biodiesel with the best properties was obtained using 15% methanol, sodium methoxide as catalyst (1%), and 60 degrees C temperature. This biodiesel has very similar properties to those of diesel no. 2.
引用
收藏
页码:2927 / 2931
页数:5
相关论文
共 15 条
[1]   Oil and paper pulp from Cynara cardunculus: preliminary results [J].
BenjellounMlayah, B ;
deLopez, S ;
Delmas, M .
INDUSTRIAL CROPS AND PRODUCTS, 1997, 6 (3-4) :233-236
[2]   TRANSESTERIFICATION KINETICS OF SOYBEAN OIL [J].
FREEDMAN, B ;
BUTTERFIELD, RO ;
PRYDE, EH .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1986, 63 (10) :1375-1380
[3]   HEATS OF COMBUSTION OF FATTY ESTERS AND TRIGLYCERIDES [J].
FREEDMAN, B ;
BAGBY, MO .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1989, 66 (11) :1601-1605
[4]   VARIABLES AFFECTING THE YIELDS OF FATTY ESTERS FROM TRANSESTERIFIED VEGETABLE-OILS [J].
FREEDMAN, B ;
PRYDE, EH ;
MOUNTS, TL .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1984, 61 (10) :1638-1643
[5]   TRANS-ESTERIFICATION INSITU OF SUNFLOWER SEED OIL [J].
HARRINGTON, KJ ;
DARCYEVANS, C .
INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1985, 24 (02) :314-318
[7]   Biodiesel fuel from animal fat. Ancillary studies on transesterification of beef tallow [J].
Ma, FR ;
Clements, LD ;
Hanna, MA .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1998, 37 (09) :3768-3771
[8]  
MORDRET F, 1994, OL CORPS GRAS LIPIDE, V1, P33
[9]  
NYE MJ, 1983, VEGETABLE OILS DIESE, V3, P78
[10]   CETANE NUMBER DETERMINATION OF SYNTHETIC DIESEL FUELS [J].
OCONNOR, CT ;
FORRESTER, RD ;
SCURRELL, MS .
FUEL, 1992, 71 (11) :1323-1327