Diamond-like carbon layers grown by electrochemical method-structural study

被引：2

作者：

Kulesza, S. ^{[1
]}

Szatkowski, J. ^{[2
]}

Lulinska, E. ^{[2
]}

Kozanecki, M. ^{[3
]}

机构：

[1] Uniwersytet Warminsko Mazurski, Wydzial Matemat & Informat Stosowanej, PL-10561 Olsztyn, Poland

[2] Uniwersytet Mikolaja Kopernika, Inst Fizyki, PL-87100 Torun, Poland

[3] Politechn Lodzka, Katedra Fizyki Mol, PL-90924 Lodz, Poland

来源：

ENERGY CONVERSION AND MANAGEMENT | 2008年 / 49卷 / 09期

关键词：

diamond-like carbon; electrolysis; structure;

D O I：

10.1016/j.enconman.2008.02.028

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

A simple method of production of diamond-like carbon (DLC) thin films on various substrates by means of electrolysis of liquid hydrocarbons under ambient conditions is described in the paper. The amount of sp(3)-hybridized carbon clusters within deposited films is a key parameter of their structural quality, and is investigated using scanning electron microscopy (SEM), and Raman spectroscopy. Obtained results indicate that although the electrolysis generally leads to granular DLC films contaminated with graphitic inclusions, providing current density larger than 520 mA cm(-2) at 1700 V, sp(3)-rich microcrystals with sharp edges can be found as well. Micro-Raman spectroscopic data strongly suggest that these microcrystals are minute diamonds, which eventually opens up a new perspective for a low-temperature synthesis of diamond-related materials. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：2487 / 2489

页数：3

共 11 条

[1] ION-BEAM DEPOSITION OF THIN FILMS OF DIAMONDLIKE CARBON [J].

AISENBERG, S ;

CHABOT, R .

JOURNAL OF APPLIED PHYSICS, 1971, 42 (07) :2953-+

[2]

Fitzer E., 1988, High Temperatures - High Pressures, V20, P449

[3] Solar cells prepared on multicrystalline silicon subjected to new gettering and passivation treatments [J].

Litovchenko, VG ;

Klyuis, NI ;

Evtukh, AA ;

Efremov, AA ;

Sarikov, AV ;

Popov, VG ;

Kostylyov, VP ;

Rasamakin, YV ;

Haessler, C ;

Koch, W .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2002, 72 (1-4) :343-351

[4] ATTEMPT TO GROW DIAMOND PHASE CARBON-FILMS FROM AN ORGANIC SOLUTION [J].

NAMBA, Y .

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1992, 10 (05) :3368-3370

[5]

OBERLIN A, 1975, PHILOS MAG, V32, P312

[6] Low voltage electrodeposition of diamond like carbon (DLC) [J].

Sreejith, K ;

Nuwad, J ;

Pillai, CGS .

APPLIED SURFACE SCIENCE, 2005, 252 (02) :296-302

[7] Investigation of phases in the carbon films deposited by electrolysis of ethanol liquid phase using Raman scattering [J].

Sun, Z ;

Sun, Y ;

Wang, X .

CHEMICAL PHYSICS LETTERS, 2000, 318 (4-5) :471-475

[8] DEPOSITION OF CARBON-FILMS BY ELECTROLYSIS OF A WATER-ETHYLENE GLYCOL SOLUTION [J].

SUZUKI, T ;

MANITA, Y ;

YAMAZAKI, T ;

WADA, S ;

NOMA, T .

JOURNAL OF MATERIALS SCIENCE, 1995, 30 (08) :2067-2069

[9] Electrodeposition of diamond-like carbon films in organic solvents using a thin wire anode [J].

Wang, H ;

Yoshimura, M .

CHEMICAL PHYSICS LETTERS, 2001, 348 (1-2) :7-10

[10] STRUCTURE AND PROPERTIES OF QUASI-AMORPHOUS FILMS PREPARED BY ION-BEAM TECHNIQUES [J].

WEISSMANTEL, C ;

BEWILOGUA, K ;

DIETRICH, D ;

ERLER, HJ ;

HINNEBERG, HJ ;

KLOSE, S ;

NOWICK, W ;

REISSE, G .

THIN SOLID FILMS, 1980, 72 (01) :19-31

← 1 2 →