Rhodium Complexes of a New Structurally Adaptive Type Ligand

被引：7
|
作者：
Wanniarachchi, Sarath [1 ]
Hewage, Jeewantha S. [1 ]
Lindeman, Sergey V. [1 ]
Gardinier, James R. [1 ]
机构：
[1] Marquette Univ, Dept Chem, Milwaukee, WI 53201 USA
来源：
ORGANOMETALLICS | 2013年 / 32卷 / 10期
关键词：
COORDINATION CHEMISTRY; REACTIVITY; ISOCYANIDE; CATALYSTS; BEARING;
D O I：
10.1021/om400151e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new PNN-pincer type ligand with pyrazolyl and diphenylphosphine flanking donors on a diarylamido anchor has been prepared. Its bis(tert-butyl isocyanide)rhodium(I) complex exhibits hemilabile behavior in solution, and its solid-state structure verified the elusive (KP)-P-2,N coordination mode for this type of ligand. Reactions between (PNN)Rh((CNBu)-Bu-t)(2) and iodomethane afford both fac- and cis,mer-[(PNN)Rh((CNBu)-Bu-t)(2)(Me)RI), which further showcases the structural versatility of the ligand.
引用
收藏
页码：2885 / 2888
页数：4
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