Synthesis, Crystal Structures and Characterization of Two Cadmium Coordination Polymers Based on a Bis(imidazole) Ligand

被引：0
|
作者：
Zhang Wei-Guo [1 ]
Gui Guang-Hua [2 ]
Jiao Cui-Huan [2 ]
Geng Jian-Chen [2 ]
机构：
[1] Hebei Normal Univ Sci & Technol, Dept Chem, Qinhuangdao 066004, Hebei, Peoples R China
[2] Hebei United Univ, Coll Chem Engn, Tangshan 063009, Hebei, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2012年 / 28卷 / 11期
关键词：
coordination polymer; crystal structure; flexible di(imidazole); (4,4) network; DIPICOLINATE; DINUCLEAR; COMPLEXES;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The two Cd(II) coordination polymers, [Cd(PhCOO)(2)(bmix)](n) (1) and {[Cd(chdc)(bmix)]center dot C2H5OH}(n) (2) (bmix=1,4-bis (2-methylimidazole-1-ylmethyl)benzene, H(2)chdc=1,4-cyclohexanedicarboxylic acid) were hydrothermally synthesized and characterized by elemental analysis, IR spectroscopy, TG and X-ray single crystal diffraction. 1 possesses a one-dimensional zigzag chain structure parallel to [001]; 2 displays a two-dimensional undulated (4,4) network constructed with bmix and chdc dianion bridge ligands. Each cadmium(II) ion in 1 and 2 has distorted octahedral coordination geometry. In addition, the thermal properties of two coordination polymers have been presented. CCDC: 842711, 1; 842712, 2.
引用
收藏
页码：2494 / 2500
页数：7
相关论文
共 18 条
  • [11] Sheldrick G. M., 1996, PROGRAM EMPIRICAL AB
  • [12] Formation of novel discrete silver(I) coordination architectures with quinoline-based monothioethers:: adjusting the intramolecular Ag•••Ag distances and complex structures by ligands modifications and variations of counter anions
    Song, RF
    Xie, YB
    Li, JR
    Bu, XH
    [J]. DALTON TRANSACTIONS, 2003, (24) : 4742 - 4748
  • [13] Spek A.L., 2000, PLATON, A Multipurpose Crystallographic Tool
  • [14] Self-Supported Catalysts
    Wang, Zheng
    Chen, Gang
    Ding, Kuiling
    [J]. CHEMICAL REVIEWS, 2009, 109 (02) : 322 - 359
  • [15] Syntheses and structures of four d10 metal-organic frameworks assembled with aromatic polycarboxylate and bix [bix=1,4-bis(imidazol-1-ylmethyl)benzene]
    Wen, LL
    Li, YZ
    Lu, ZD
    Lin, JG
    Duan, CY
    Meng, QJ
    [J]. CRYSTAL GROWTH & DESIGN, 2006, 6 (02) : 530 - 537
  • [16] Porous Phosphorescent Coordination Polymers for Oxygen Sensing
    Xie, Zhigang
    Ma, Liqing
    deKrafft, Kathryn E.
    Jin, Athena
    Lin, Wenbin
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (03) : 922 - +
  • [17] Four novel 3D copper(II) coordination polymers with different topologies
    Yang, J
    Ma, JF
    Liu, YY
    Li, SL
    Zheng, GL
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (11) : 2174 - 2180
  • [18] 1D, 2D, and 3D Metal-Organic Frameworks Based on Bis(imidazole) Ligands and Polycarboxylates: Syntheses, Structures, and Photoluminescent Properties
    Zhang, Lai-Ping
    Ma, Jian-Fang
    Yang, Jin
    Liu, Ying-Ying
    Wei, Guo-Hua
    [J]. CRYSTAL GROWTH & DESIGN, 2009, 9 (11) : 4660 - 4673
12