Molecular Organic Crystals: From Barely Porous to Really Porous

被引：81
作者：
Cooper, Andrew I. [1 ,2 ]
机构：
[1] Univ Liverpool, Dept Chem, Liverpool L69 3BX, Merseyside, England
[2] Univ Liverpool, Ctr Mat Discovery, Liverpool L69 3BX, Merseyside, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 32期
基金：
英国工程与自然科学研究理事会;
关键词：
crystal engineering; hydrogen bonding; nanoporous materials; organic crystals; supramolecular materials; SURFACE-AREA; HYDROGEN ADSORPTION; GAS-STORAGE; FRAMEWORK; POROSITY; METHANE; CONSTRUCTION; NETWORKS; NITROGEN; DESIGN;
D O I：
10.1002/anie.201203117
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Holey suitable crystals: A trisbenzimidazolone molecule self-assembles by hydrogen bonding to form a permanently porous crystal with an apparent surface area, SA BET, of 2796 m 2 g -1 (see scheme), demonstrating that extrinsic, intermolecular porosity is a viable strategy for highly porous materials. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：7892 / 7894
页数：3
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