Improved Oxidative Cleavage of Lignin Model Compound by ORR in Protic Ionic Liquid

被引：26
|
作者：
Jiang, Haomin [1 ]
Wang, Lei [1 ]
Qiao, Lingling [1 ]
Xue, Aiguo [1 ]
Cheng, Yujuan [1 ]
Chen, Yueying [1 ]
Ren, Yuan [1 ]
Chen, Yongmei [1 ]
Wan, Pingyu [1 ]
机构：
[1] Beijing Univ Chem Technol, Fac Sci, Inst Appl Electrochem, Beijing 100029, Peoples R China
来源：
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE | 2019年 / 14卷 / 03期
基金：
北京市自然科学基金;
关键词：
p-benzyloxyl phenol (PBP); oxygen reduction reaction (ORR); protic ionic liquid (PIL); lignin depolymerization; reactive oxygen species (ROS); OXYGEN REDUCTION REACTION; ELECTROCHEMICAL OXIDATION; DIMETHYL-SULFOXIDE; SUPEROXIDE ION; ASPEN LIGNIN; KRAFT LIGNIN; DEGRADATION; CONVERSION; ELECTRODE; DEPOLYMERIZATION;
D O I：
10.20964/2019.03.10
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The electrochemical degradation of p-benzyloxyl phenol (PBP) in [HNEt3][HSO4] is investigated using an oxygen reductive reaction (ORR) cathode in a non-membrane cell. It is disclosed that the two-electron reductive products of O-2 (that is H2O2) is the main reactive oxygen species (ROS) in [HNEt3][HSO4], a protic ionic liquid (PIL). The degradation of PBP in PIL with the degradation rate of 48.2% and the current efficiency of 29.5% are obtained, which is higher than that in [BMIM][BF4], an aprotic ionic liquid (AIL). Based on the products identified by GC-MS, the effect of electro-generated H2O2 on the cleavage of ether bond in PBP is proposed. The result confirms that the appropriate number of protons in supporting electrolyte plays an important role in electrochemical degradation of lignin model compounds.
引用
收藏
页码：2645 / 2654
页数：10
相关论文
共 50 条
  • [31] Oxidative cleavage of C-O and benzene ring in lignin catalyzed by polyoxometalate ionic liquids
    Lin, Zeying
    Zheng, Xinlai
    Long, Jinxing
    Liu, Sijie
    Li, Xuehui
    Huagong Xuebao/CIESC Journal, 2020, 71 (12): : 5541 - 5550
  • [32] Cleavage of the -O-4 bond in a lignin model compound using the acidic ionic liquid 1-H-3-methylimidazolium chloride as catalyst: a DFT mechanistic study
    Zhu, Youtao
    Han, Zhe
    Fu, Lijun
    Liu, Chengbu
    Zhang, Dongju
    JOURNAL OF MOLECULAR MODELING, 2018, 24 (11)
  • [33] Improved ionic model of liquid uranium dioxide
    Gryaznov, V
    Iosilevski, I
    Yakub, E
    Fortov, V
    Hyland, GJ
    Ronchi, C
    JOURNAL DE PHYSIQUE IV, 2000, 10 (P5): : 363 - 367
  • [34] Efficient oxidative cleavage of lignin C-C model compound using MOF-derived Cobalt/Nickel sulfide heterostructures
    Wang, Na
    Xue, Rong
    Yang, Na
    Sun, Hao
    Zhang, Baoyong
    Ma, Zhongmin
    Ma, Yunqian
    Zang, Lihua
    Journal of Alloys and Compounds, 2022, 929
  • [35] Efficient oxidative cleavage of lignin C-C model compound using MOF-derived Cobalt/Nickel sulfide heterostructures
    Wang, Na
    Xue, Rong
    Yang, Na
    Sun, Hao
    Zhang, Baoyong
    Ma, Zhongmin
    Ma, Yunqian
    Zang, Lihua
    JOURNAL OF ALLOYS AND COMPOUNDS, 2022, 929
  • [36] Exploring the Photocatalytic Cleavage Pathway of the β-5 Linkage Lignin Model Compound on Carbon Nitride
    Liu, Junhong
    Ralphs, Kathryn
    Murnaghan, Christopher W. J.
    Skillen, Nathan
    Sheldrake, Gary N.
    McCarron, Philip
    Robertson, Peter K. J.
    CHEMSUSCHEM, 2025, 18 (03)
  • [37] On the product selectivity in the electrochemical reductive cleavage of 2-phenoxyacetophenone, a lignin model compound
    da Cruz, Marcia Gabriely A.
    Rodrigues, Bruno V. M.
    Ristic, Andjelka
    Budnyk, Serhiy
    Das, Shoubhik
    Slabon, Adam
    GREEN CHEMISTRY LETTERS AND REVIEWS, 2022, 15 (01) : 151 - 159
  • [38] ADHESIVE FEEDSTOCKS FROM LIGNIN - MECHANISTIC STUDIES ON THE OXIDATIVE-CLEAVAGE REACTION OF SOME LIGNIN MODEL COMPOUNDS
    SCHULTZ, TP
    FISHER, TH
    DERSHEM, SM
    ACS SYMPOSIUM SERIES, 1989, 385 : 68 - 81
  • [39] Iron-catalysed oxidative cleavage of lignin and β-O-4 lignin model compounds with peroxides in DMSO
    Mottweiler, Jakob
    Rinesch, Torsten
    Besson, Claire
    Buendia, Julien
    Bolm, Carsten
    GREEN CHEMISTRY, 2015, 17 (11) : 5001 - 5008
  • [40] A comparison of the oxidation of lignin model compounds in conventional and ionic liquid solvents and application to the oxidation of lignin
    Yao, Soledad G.
    Meier, Mark S.
    Pace, Robert B., III
    Crockera, Mark
    RSC ADVANCES, 2016, 6 (106) : 104742 - 104753
12345