Enhanced photocatalytic activity and reaction mechanism of Ag-doped α-Bi2O3 nanosheets

被引:12
作者
Shan, Lianwei [1 ]
Ding, Jun [1 ]
Sun, Wenli [1 ]
Han, Zhidong [1 ]
Jin, Liguo [1 ]
机构
[1] Harbin Univ Sci & Technol, Coll Mat Sci & Engn, Harbin 150040, Heilongjiang, Peoples R China
关键词
Bismuth oxide; nanosheet; photocatalytic activities; Ag doping; scavenger; BAND ALIGNMENT; DEGRADATION; BIVO4; HETEROJUNCTION; OXYGEN; BI2O3; WATER; HETEROSTRUCTURES; NANOCRYSTALS; PERFORMANCE;
D O I
10.1080/24701556.2017.1357590
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The alpha-Bi2O3 and Ag-doped nanosheets were successfully prepared via a citric method. Based on the sodium oxalate scavenger, it was inferred that the hole plays a key role in the photooxidation process for silver-doped Bi2O3. Combined further with the IR analysis, it is found that the center dot O-2(-) has an effect on the decolorization of methylene blue (MB) under visible-light irradiation. The O-2/H2O2 electrode could contribute to the separation of electron-hole pairs due to the electrons flowing from CB to this electrode. As a result, the doped Ag species greatly affected the photocatalytic activities of Bi2O3 by the oxidative decolorization of MB.
引用
收藏
页码:1625 / 1634
页数:10
相关论文
共 66 条
[21]   In situ synthesis of α-β phase heterojunction on Bi2O3 nanowires with exceptional visible-light photocatalytic performance [J].
Hou, Jungang ;
Yang, Chao ;
Wang, Zheng ;
Zhou, Weilin ;
Jiao, Shuqiang ;
Zhu, Hongmin .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2013, 142 :504-511
[22]   Photocatalytic degradation of methyl orange using α-Bi2O3 prepared without surfactant [J].
Iyyapushpam, S. ;
Nishanthi, S. T. ;
Padiyan, D. Pathinettam .
JOURNAL OF ALLOYS AND COMPOUNDS, 2013, 563 :104-107
[23]   Location and State of Pt in Platinized CdS/TiO2 Photocatalysts for Hydrogen Production from Water under Visible Light [J].
Jang, Jum Suk ;
Choi, Sun Hee ;
Kim, Hyun Gyu ;
Lee, Jae Sung .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (44) :17200-17205
[24]   Crystalline metallic Au nanoparticle-loaded α-Bi2O3 microrods for improved photocatalysis [J].
Jiang, Hai-Ying ;
Cheng, Kun ;
Lin, Jun .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (35) :12114-12121
[25]   Shape control of semiconductor and metal oxide nanocrystals through nonhydrolytic colloidal routes [J].
Jun, Young-wook ;
Choi, Jin-sil ;
Cheon, Jinwoo .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (21) :3414-3439
[26]   Optical and phonon properties of Sm-doped α-Bi2O3 micro rods [J].
Karthikeyan, Balasubramanian ;
Udayabhaskar, R. ;
Kishore, Ashwin .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2014, 117 (03) :1409-1414
[27]   Electrochemical and photoelectrochemical investigation of single-crystal anatase [J].
Kavan, L ;
Gratzel, M ;
Gilbert, SE ;
Klemenz, C ;
Scheel, HJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (28) :6716-6723
[28]   Unusual reactivity of visible-light-responsive AgBr-BiOBr heterojunction photocatalysts [J].
Kong, Liang ;
Jiang, Zheng ;
Lai, Henry H. ;
Nicholls, Rebecca J. ;
Xiao, Tiancun ;
Jones, Martin O. ;
Edwards, Peter P. .
JOURNAL OF CATALYSIS, 2012, 293 :116-125
[29]   Two-step hydrothermal process for synthesis of F-doped BiVO4 spheres with enhanced photocatalytic activity [J].
Li, Jun-Qi ;
Guo, Zhan-Yun ;
Liu, Hui ;
Du, Juan ;
Zhu, Zhen-Feng .
JOURNAL OF ALLOYS AND COMPOUNDS, 2013, 581 :40-45
[30]   Spatial separation of photogenerated electrons and holes among {010} and {110} crystal facets of BiVO4 [J].
Li, Rengui ;
Zhang, Fuxiang ;
Wang, Donge ;
Yang, Jingxiu ;
Li, Mingrun ;
Zhu, Jian ;
Zhou, Xin ;
Han, Hongxian ;
Li, Can .
NATURE COMMUNICATIONS, 2013, 4