Synthesis and Characterization of [2.2]Paracyclophane-Containing Conjugated Microporous Polymers

被引：8

作者：

Morisaki, Yasuhiro ^{[1
]}

Gon, Masayuki ^{[1
]}

Tsuji, Yuichi ^{[1
]}

Kajiwara, Yuichi ^{[1
]}

Chujo, Yoshiki ^{[1
]}

机构：

[1] Kyoto Univ, Dept Polymer Chem, Grad Sch Engn, Nishikyo Ku, Kyoto 6158510, Japan

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2012年 / 213卷 / 05期

关键词：

cyclophanes; conjugated microporous polymers; surface area; HIGH-SURFACE-AREA; ORDERED MESOPOROUS MATERIALS; ORGANIC POLYMERS; HYDROGEN STORAGE; BUILDING-BLOCKS; METHANE; DESIGN; SPACE; FRAMEWORKS; CHEMISTRY;

D O I：

10.1002/macp.201100563

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Conjugated microporous polymers (CMPs) are prepared from disubstituted and tetrasubstituted [2.2]paracyclophane monomers by a SonogashiraHagihara coupling. The polymers obtained exhibit a type I nitrogen gas adsorption profile and H4-like hysteresis loops, indicating that the [2.2]paracyclophane-containing CMPs possess slit-like mesopores. Their BrunauerEmmettTeller surface areas are estimated to be above 500 m2 g-1. The step and stacked structure of the [2.2]paracyclophane unit affects the morphology of the polymers because of the contribution of two-dimensional expansion of the polymer network.

引用

页码：572 / 579

页数：8

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