Silica-supported bismuth(III) chloride as a new recyclable heterogeneous catalyst for the Paal-Knorr pyrrole synthesis

被引：63

作者：

Aghapoor, Kioumars ^{[1
]}

Ebadi-Nia, Leila ^{[1
]}

Mohsenzadeh, Farshid ^{[1
]}

Morad, Mina Mohebi ^{[1
]}

Balavar, Yadollah ^{[1
]}

Darabi, Hossein Reza ^{[1
]}

机构：

[1] Chem & Chem Engn Res Ctr Iran, Nano & Organ Synth Lab, Tehran 1496813151, Iran

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2012年 / 708卷

关键词：

BiCl3/SiO2; Heterogeneous Lewis acid catalyst; Paal-Knorr reaction; Pyrrole; SOLVENT-FREE CONDITIONS; SUBSTITUTED PYRROLES; SOLID ACIDS; MYCOBACTERIUM-TUBERCULOSIS; ASSISTED SYNTHESIS; ORGANIC-SYNTHESIS; MILD CONDITIONS; CONDENSATION; ANTIMYCOBACTERIAL; ROSEOPHILIN;

D O I：

10.1016/j.jorganchem.2012.02.008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Silica-supported bismuth(III) chloride (BiCl3/SiO2) acts as as a highly efficient heterogeneous Lewis acid catalyst for the Paal-Knorr pyrrole synthesis in hexane at room temperature. The catalyst exhibited remarkable reusable activity and higher catalytic performance than homogeneous BiCl3. A plausible mechanism for the catalytic action of BiCl3/SiO2 has been introduced. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：25 / 30

页数：6

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