Catalytic oxidation of alcohols into aldehydes and ketones by an osmium-copper bifunctional system using molecular oxygen

被引：66

作者：

Coleman, KS ^{[1
]}

Coppe, M ^{[1
]}

Thomas, C ^{[1
]}

Osborn, JA ^{[1
]}

机构：

[1] Univ Strasbourg 1, Inst Le Bel, Lab Chim Met Transit & Catalyse, CNRS,UMR 7513, F-67070 Strasbourg, France

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 19期

关键词：

D O I：

10.1016/S0040-4039(99)00598-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The oxidation of allylic and benzylic alcohols to aldehydes can be carried out at room temperature as low as 25 degrees C with molecular oxygen, in the presence of the bifunctional osmium-copper system OsO4-CuCl acting as the catalyst. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

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页码：3723 / 3726

页数：4

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