Dynamic Behavior of M6L4 Capsules in Solution and Crystalline States

被引:12
作者
Ning, Guo-Hong [1 ]
Inokuma, Yasuhide [1 ]
Fujita, Makoto [1 ]
机构
[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan
关键词
coordination networks; host-guest chemistry; molecular capsules; x-ray crystallography; ENCAPSULATION; COMPLEXES; MOLECULES; ABILITY; CAGES;
D O I
10.1002/asia.201300758
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The perfect host: A discrete Ru6L4 capsule was synthesized as a solution counterpart of networked Co6L4 capsules, which can host various guests in the crystalline state using dynamic conformational changes. By harnessing the common dynamic nature of two hosts upon guest encapsulation, the solution host-guest chemistry of the Ru 6L4 capsule was transferred into the crystalline state using networked Co6L4 capsules. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:2596 / 2599
页数:4
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