Solubility of 4-Methylsulfonylacetophenone in Nine Pure Solvents and (Ethyl Acetate plus n-Hexane) Binary Solvent Mixtures from 278.15 K to 328.15 K

被引：4
|
作者：
Hao, Jianfeng [1 ]
Yang, Wenge [1 ]
Li, Hongjie [1 ]
Fan, Shimin [1 ]
Zhao, Wangdan [1 ]
Hu, Yonghong [2 ]
机构：
[1] Nanjing Tech Univ, Sch Pharmaceut Sci, 30,South Puzhu Rd, Nanjing 211816, Jiangsu, Peoples R China
[2] Nanjing Tech Univ, State Key Lab Mat Oriented Chem Engn, 200,South Zhongshan Rd, Nanjing 210009, Jiangsu, Peoples R China
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2017年 / 62卷 / 01期
关键词：
THERMODYNAMIC MODELS; WATER; METHANOL; ETHANOL; TEMPERATURES; SOLIDS; ACID;
D O I：
10.1021/acs.jced.6b00617
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
We focus on the solubility of 4-methylsulfonylacetophenone. A gravimetric method was taken to measure the solubility of 4-methylsulfonylacetophenone in n-hexane, ethyl acetate, methanol, ethanol, n-propyl alcohol, n-butyl alcohol, ethylene glycol, cyclohexane, isobutyl alcohol, and (ethyl acetate + n-hexane) binary solvent mixtures from 278.15 K to 328.15 K under atmospheric pressure. Its corresponding (solid + liquid) equilibrium results will provide essential support for further theoretical studies. The solubility of 4-methylsulfonylacetophenone in nine pure solvents were correlated with lambda h and Apelblat models, while 4-methylsulfonylacetophenone in (ethyl acetate + n-hexane) binary solvent mixtures were correlated with the Apelblat and CNIBS/R-K models. The Apelblat model was proven to be the best-fit model for correlating the solubility of both pure solvents and binary solvents mixtures from the analysis of the STATISTIC.
引用
收藏
页码：236 / 242
页数：7
相关论文
共 50 条
  • [1] Solubility of Valsartan in Ethyl Acetate plus Hexane Binary Mixtures from (278.15 to 313.15) K
    Liu, Yan
    Wang, Jingkang
    Wang, Xiaobo
    Pang, Fei
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2009, 54 (04): : 1412 - 1414
  • [2] Solubility of succinic anhydride in different pure solvents and binary solvent mixtures with the temperature range from 278.15 to 333.15 K
    Yang, Wenge
    Chen, Zhaoguo
    Jiang, Xinmin
    Hu, Yonghong
    Li, Yonglan
    Shi, Yulan
    Wang, Jikui
    JOURNAL OF MOLECULAR LIQUIDS, 2013, 180 : 7 - 11
  • [3] Experimental and thermodynamic analysis on the solubility of valsartan in ethyl acetate plus (butanone, isopropyl ether) binary solvent mixtures (from 278.15 to 323.15 K)
    Wang, Qingqing
    Shen, Mangmang
    Cheng, Rong
    Yang, Asan
    Zheng, Yanping
    Sun, Qin
    PHYSICS AND CHEMISTRY OF LIQUIDS, 2017, 55 (01) : 38 - 50
  • [4] Measurement and correlation of solubility of ε-CL-20 in solvent mixtures of (chloroform plus ethyl acetate) and (m-xylene plus ethyl acetate) at temperatures from 278.15 K to 313.15 K
    Lv, Penghao
    Tong, Yao
    Wang, Huiyun
    Dang, Leping
    Sun, Chenghui
    Pang, Si Ping
    JOURNAL OF MOLECULAR LIQUIDS, 2017, 231 : 192 - 201
  • [5] Solubility measurement and solvent effect of Doxofylline in pure solvents and mixtures solvents at 278.15-323.15K
    Shen, Yanmin
    Liu, Wenju
    Sun, Chen
    Yao, TianTian
    Bao, Zehua
    JOURNAL OF MOLECULAR LIQUIDS, 2020, 307
  • [6] Solubility and Thermodynamic Modeling of Sulfanilamide in 12 Mono Solvents and 4 Binary Solvent Mixtures from 278.15 to 318.15 K
    Kodide, Kalyani
    Asadi, Prashanth
    Thati, Jyothi
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2019, 64 (12): : 5196 - 5209
  • [7] Solubility and thermodynamic parameters of 5-Fluoro-2-oxindole in nine pure solvents and binary solvent mixtures at T = (278.15-323.15) K
    Zhao, Guomin
    Deng, Zhenmei
    Yang, Wenge
    Li, Fangzhao
    Wang, Li
    Song, Yiyi
    Zhao, Xinxin
    Sheng, Huace
    Hu, Yonghong
    JOURNAL OF MOLECULAR LIQUIDS, 2020, 298
  • [8] Determination and Correlation of Solubility of Carvedilol in Six Pure Solvents and Three Binary Solvent Mixtures at T=278.15-313.15 K
    Ou, Ru Peng
    Wang, Xin Xian
    Lu, Ding Qiang
    Ye, Hui
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2020, 65 (07): : 3472 - 3481
  • [9] Solubility of Valsartan in Different Organic Solvents and Ethanol plus Water Binary Mixtures from (278.15 to 313.15) K
    Liu, Yan
    Wang, Jingkang
    Wang, Xiaobo
    Liu, Peng
    Pang, Fei
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2009, 54 (03): : 986 - 988
  • [10] Measurement and correlation of solubility data for albendazole in ten pure solvents and two binary solvent systems from 278.15 K to 323.15 K
    Wu, Yunjie
    Chen, Yang
    Xu, Ke
    Li, Nanxin
    Fu, Hualin
    Wang, Xianxiang
    Xu, Funeng
    Li, Haohuan
    Shu, Gang
    Lin, Juchun
    Liang, Xiaoxia
    Zhang, Wei
    SUSTAINABLE CHEMISTRY AND PHARMACY, 2022, 27
12345