Recent Advances in the Regio- and Stereospecific Cyclopolymerization of ,-Diynes by Tailored Ruthenium Alkylidenes and Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes

被引：32

作者：

Buchmeiser, Michael R. ^{[1
,2
]}

机构：

[1] Univ Stuttgart, Inst Polymer Chem, Pfaffenwaldring 55, D-70569 Stuttgart, Germany

[2] Inst Text Chem & Chem Fibers, Korschtalstr 26, Denkendorf, Germany

来源：

POLYMER REVIEWS | 2017年 / 57卷 / 01期

关键词：

Molybdenum; ruthenium; cyclopolymerization; conjugated polymers; N-heterocyclic carbene (NHC); tacticity; RING-OPENING METATHESIS; ELECTRON-WITHDRAWING LIGANDS; TRANSITION-METAL CATALYSTS; OLEFIN METATHESIS; STEREOSELECTIVE CYCLOPOLYMERIZATION; LIVING POLYMERIZATION; REGIOSELECTIVE CYCLOPOLYMERIZATION; 1,7-OCTADIYNE DERIVATIVES; CLOSING METATHESIS; FACTORS RELEVANT;

D O I：

10.1080/15583724.2015.1136643

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Recent accomplishments in the cyclopolymerization of ,-diynes by tailored Ru- and Mo-alkylidenes are reported. Special emphasis is put on the extent and origin of both stereo- and regioselectivity with the different initiator systems used. Particularly, the very recently developed molybdenum imido alkylidene N-heterocyclic carbene (NHC) complexes are of utmost interest since they allow for the cyclopolymerization of ,-diynes bearing protic functional groups such as hydroxyls and carboxylic acids and therefore rival Ru-alkylidenes both in terms of regio- and stereoselectivity but also in terms of activity and functional group tolerance.

引用

页码：15 / 30

页数：16

共 92 条

[1] CYCLOPOLYMERIZATION OF 4,4-DIPHENOXY-1,6-HEPTADIYNE BY TRANSITION-METAL CATALYSTS [J].

AHN, HK ;

KIM, YH ;

JIN, SH ;

CHOI, SK .

POLYMER BULLETIN, 1992, 29 (06) :625-632

[2]

Akopyan L. A., 1977, ARM KHIM ZH, V30, P771

[3] Regio- and stereospecific cyclopolymerization of 1,6-heptadiynes and 1,5-hexadiynes [J].

Anders, U ;

Krause, JO ;

Wang, DR ;

Nuyken, O ;

Buchmeiser, MR .

DESIGNED MONOMERS AND POLYMERS, 2004, 7 (1-2) :151-163

[4] Regio- and stereospecific cyclopolymerization of 1,6-heptadiynes [J].

Anders, U ;

Nuyken, O ;

Buchmeiser, MR .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 213 (01) :89-92

[5] Fine-tuning of molybdenum imido alkylidene complexes for the cyclopolymerization of 1,6-heptadiynes to give polyenes containing exclusively five-membered rings [J].

Anders, U ;

Nuyken, O ;

Buchmeiser, MR ;

Wurst, K .

MACROMOLECULES, 2002, 35 (24) :9029-9038

[6]

Anders U, 2002, ANGEW CHEM INT EDIT, V41, P4044, DOI 10.1002/1521-3773(20021104)41:21<4044::AID-ANIE4044>3.0.CO

[7]

2-M

[8]

Anderson E. B., 2011, SYNLETT, V23, P185

[9] p-Doping and Fiber Spinning of Poly(heptadiyne)s [J].

Anderson, Emily B. ;

Kumar, P. Santosh ;

Schawaller, Dirk ;

Mavila, Sudheendran ;

Voss, Michael ;

Freyer, Anette ;

Knolle, Wolfgang ;

Hermanutz, Frank ;

Buchmeiser, Michael R. .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 2013, 214 (09) :1047-1051

[10] Reactivity of the Dicationic Ruthenium-Alkylidene Complex [Ru(DMF)3(IMesH2)(=CH-2-(2-PrO)-C6H4)],2+(BF4-)2] in Ring-Opening Metathesis and Cyclopolymerization [J].

Autenrieth, Benjamin ;

Anderson, Emily Baird ;

Wang, Dongren ;

Buchmeiser, Michael R. .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 2013, 214 (01) :33-40

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