An inorganic-organic composite framework with an unprecedented 3D heterometallic inorganic connectivity and white-light emission

被引：49
作者：
Zhang, Huabin [1 ,2 ]
Lin, Ping [1 ]
Shan, Xiaochen [1 ,2 ]
Du, Fenglei [1 ,2 ]
Li, Qipeng [1 ,2 ]
Du, Shaowu [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 22期
基金：
中国国家自然科学基金;
关键词：
MICROPOROUS METAL; BUILDING-BLOCKS; LUMINESCENT; CHANNELS;
D O I：
10.1039/c3cc38655d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The first example of an inorganic-organic composite framework with a 3D inorganic Cd-O-M (M = Cd, Rb) connectivity, featuring a unique {Cd7Rb}(n) helix and nanoscale {Cd16Rb4} and {Cd18Rb2} rings, has been constructed and structurally characterized. This compound exhibits white-light emission and a wavelength-dependent photochromic response.
引用
收藏
页码：2231 / 2233
页数：3
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