Synthesis and solvent-dependent properties of Ru(acac)2dppz

被引：25

作者：

Nair, RB ^{[1
]}

Yeung, LK ^{[1
]}

Murphy, CJ ^{[1
]}

机构：

[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 10期

关键词：

D O I：

10.1021/ic981322v

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first neutral monosubstituted dipyridophenazine complex of ruthenium(II), Ru(acac)(2)dppz, has been synthesized, and its optical and electrochemical properties have been studied. The energy of the metal-to-ligand charge-transfer transition of the complex in solution is linearly dependent on the solvent's polarity. The complex is insoluble in water and nonemissive at both room temperature and at 77 K.

引用

页码：2536 / +

页数：4

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