Strontium titanium trioxide doped magnetic graphene oxide as a nanocatalyst for biodiesel production from waste cooking oil

被引:17
作者
Jume, Binta Hadi [1 ]
Ahranjani, Parham Joolaei [2 ]
Saei, Sara Farshineh
Mahmood, Firas Muhammad Zeki [3 ]
Vasseghian, Yasser [4 ,5 ]
Rezania, Shahabaldin [6 ]
机构
[1] Univ Hafr Al Batin, Coll Sci, Dept Chem, POB 1803, Al Jamiah Dist, Saudi Arabia
[2] Katholieke Univ Leuven, Fac Biosci Engn, Dept Microbial & Mol Syst, Kasteelpk Arenberg 20,Box 2300, B-3001 Leuven, Belgium
[3] SUNY Binghamton, Dept Chem, 4400 Vestal Pkwy East, Binghamton, NY 13902 USA
[4] Soongsil Univ, Dept Chem, Seoul 06978, South Korea
[5] SIMATS, Saveetha Sch Engn, Dept Sustainable Engn, Chennai 602105, Tamil Nadu, India
[6] Sejong Univ, Environm & Energy Dept, Seoul 05006, South Korea
关键词
SrTiO3; nanoparticles; Iron oxide nanoparticles; Graphene oxide; Waste cooking oil (WCO); Heterogeneous catalyst; HETEROGENEOUS CATALYST;
D O I
10.1016/j.seta.2022.102619
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In the synthesis of biodiesel, the revelation of innovative heterogeneous catalyst substances with distinct chemical/physical characteristics has gained considerable interest. The purpose of this study was to evaluate the potential of bimetal layered strontium-titanium trioxide (SrTiO3) doped on graphene oxide-based iron oxide nanoparticles as a novel heterogeneous catalyst (IGO@SrTi) for the production of biodiesel from acidic waste cooking oil (WCO). The morphology of IGO@SrTi nanocomposite was characterized using SEM, EDX, XRD, and FT-IR.. In addition, various parameters such as the molar proportion of feedstock to methanol, reaction temperature, and contact time were examined. The ranges for influence factors were reaction temperature (25-120 degrees C), methanol/oil (M/O) mole fraction (1:1-10:1), contacting duration (10-180 min), and catalyst concentration (0.01-0.5 g). Within 180 min, using a 10:1 M ratio of methanol to oil and a reaction temperature of 120 degrees C, a 96 % FAME production was achieved using 10 wt% catalysts under the reaction conditions. The findings indicated that the IGO@SrTi nanocomposite can be employed successfully as a stable heterogeneous catalyst under the optimum condition with excellent catalytic efficiency (>90 %) and simplicity in separation.
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页数:7
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