Encapsulation of polyoxometalates within layered metal-organic frameworks with topological and pore control

被引：7

作者：

He, Zhi ^{[1
]}

Pang, Qingqing ^{[1
]}

Rankine, Damien ^{[2
]}

Sumby, Christopher J. ^{[2
]}

Zhang, Lijuan ^{[3
]}

Doonan, Christian J. ^{[2
]}

Li, Qiaowei ^{[1
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

[2] Univ Adelaide, Sch Chem & Phys, Adelaide, SA 5005, Australia

[3] Fudan Univ, Adv Mat Lab, Shanghai 200433, Peoples R China

来源：

CRYSTENGCOMM | 2013年 / 15卷 / 45期

基金：

澳大利亚研究理事会; 中国国家自然科学基金;

关键词：

COORDINATION POLYMER; PHOSPHOTUNGSTIC ACID; DESIGN; CATALYST; MIL-101; STORAGE;

D O I：

10.1039/c3ce41136b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Organic links of varied structure metrics and functionalities connect with Cu-2(COO)(4) clusters to afford layered metal-organic frameworks. Through topological and pore control, polyoxometalates could be synthetically encapsulated within the cavities. The templating effects of polyoxometalates and specific link functionalizations provide two strategies for controllably incorporating these active species into frameworks.

引用

页码：9340 / 9343

页数：4

共 41 条

[1] RETRACTED: A late-transition metal oxo complex: K7Na9[O=PtIV(H2O)L2]. L = [PW9O34]9- (Retracted Article) [J].

Anderson, TM ;

Neiwert, WA ;

Kirk, ML ;

Piccoli, PMB ;

Schultz, AJ ;

Koetzle, TF ;

Musaev, DG ;

Morokuma, K ;

Cao, R ;

Hill, CL .

SCIENCE, 2004, 306 (5704) :2074-2077

[2] Kinetically Controlled Porosity in a Robust Organic Cage Material [J].

Avellaneda, Antonio ;

Valente, Peter ;

Burgun, Alexandre ;

Evans, Jack D. ;

Markwell-Heys, Adrian W. ;

Rankine, Damien ;

Nielsen, David J. ;

Hill, Matthew R. ;

Sumby, Christopher J. ;

Doonan, Christian J. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (13) :3746-3749

[3] Direct Observation of Molecular-Level Template Action Leading to Self-Assembly of a Porous Framework [J].

Bajpe, Sneha R. ;

Kirschhock, Christine E. A. ;

Aerts, Alexander ;

Breynaert, Eric ;

Absillis, Gregory ;

Parac-Vogt, Tatjana N. ;

Giebeler, Lars ;

Martens, Johan A. .

CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (13) :3926-3932

[4] An organo-ruthenium grafted zinc-substituted tungstoarsenate [J].

Bi, Li-Hua ;

Hou, Guang-Feng ;

Wu, Li-Xin ;

Kortz, Ulrich .

CRYSTENGCOMM, 2009, 11 (08) :1532-1535

[5] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].

Chui, SSY ;

Lo, SMF ;

Charmant, JPH ;

Orpen, AG ;

Williams, ID .

SCIENCE, 1999, 283 (5405) :1148-1150

[6] Metal-Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal-Organic Materials [J].

Cook, Timothy R. ;

Zheng, Yao-Rong ;

Stang, Peter J. .

CHEMICAL REVIEWS, 2013, 113 (01) :734-777

[7] Industrial applications of metal-organic frameworks [J].

Czaja, Alexander U. ;

Trukhan, Natalia ;

Mueller, Ulrich .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1284-1293

[8] Taxonomy of periodic nets and the design of materials [J].

Delgado-Friedrichs, Olaf ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (09) :1035-1043

[9] Large-Pore Apertures in a Series of Metal-Organic Frameworks [J].

Deng, Hexiang ;

Grunder, Sergio ;

Cordova, Kyle E. ;

Valente, Cory ;

Furukawa, Hiroyasu ;

Hmadeh, Mohamad ;

Gandara, Felipe ;

Whalley, Adam C. ;

Liu, Zheng ;

Asahina, Shunsuke ;

Kazumori, Hiroyoshi ;

O'Keeffe, Michael ;

Terasaki, Osamu ;

Stoddart, J. Fraser ;

Yaghi, Omar M. .

SCIENCE, 2012, 336 (6084) :1018-1023

[10] Hybrid Organic-Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications [J].

Dolbecq, Anne ;

Dumas, Eddy ;

Mayer, Cedric R. ;

Mialane, Pierre .

CHEMICAL REVIEWS, 2010, 110 (10) :6009-6048

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