The Synthesis, Crystal Structures, and Thermal Properties of a New Zn(II) Coordination Polymer With Malonic Acid

被引：3

作者：

Zhu, Hong-Lin ^{[1
]}

Zheng, Yue-Qing ^{[1
]}

机构：

[1] Ningbo Univ, Ctr Appl Solid State Chem Res, Ningbo 315211, Zhejiang, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2012年 / 42卷 / 05期

关键词：

4; '-dipyridyldisulfide; coordination polymer; crystal structure; malonic acid; Zn(II); MAGNETIC-PROPERTIES; SEPARATION; COMPLEXES;

D O I：

10.1080/15533174.2011.615073

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of malonic acid (HOOCCH2COOH), Zn(NO3)(2)center dot 6H(2)O, 4,4'-dipyridyldisulfide (bpds) and NaOH in aqueous methanol solution under ambient conditions yielded a new complex Zn-2(bpds)(2)(C3H2O4)(2)(H2O)(2). The complex has been characterized by single-crystal X-ray diffraction, IR spectroscopy, TG-DTA analyses, elemental analyses, and powder X-ray diffraction. The Zn atoms are octahedrally coordinated by one nitrogen atom and five oxygen atoms to complete a ZnNO5 octahedra, which is bridged by malonato ligands to generate 2D sheets with the bpds acted as terminal ligand. The resulting 2D sheets are stacked in an center dot center dot center dot ABABAB center dot center dot center dot sequence due to van der Waals forces.

引用

页码：736 / 740

页数：5

共 14 条

[1] Structural evidence for metalloaromaticity in a new molecular complex with the divergent ligand 4,4′-dipyridyldisulfide [J].

Carballo, Rosa ;

Covelo, Berta ;

Fernandez-Hermida, Nuria ;

Belen Lago, Ana ;

Vazquez-Lopez, Ezequiel M. .

JOURNAL OF MOLECULAR STRUCTURE, 2009, 936 (1-3) :87-91

[2] Functional porous coordination polymers [J].

Kitagawa, S ;

Kitaura, R ;

Noro, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (18) :2334-2375

[3] Synthesis and characterization of two manganese(II) complexes containing di(4-pyridyl)sulfide (4-DPS) ligand: The effects of the counter ion and of the weak non-covalent interactions in the crystal structures of [Mn(4-DPS)4(H2O)2](ClO4)2.H2O and {[Mn(4-DPS)2(NCS)2]•2H2O}n [J].

Marinho, Maria Vanda ;

Yoshida, Maria Irene ;

Krambrock, Klaus ;

De Oliveira, Luiz Fernando C. ;

Diniz, Renata ;

Machado, Flavia C. .

JOURNAL OF MOLECULAR STRUCTURE, 2009, 923 (1-3) :60-66

[4] New trends of molecular magnetism [J].

Mrozinski, J .

COORDINATION CHEMISTRY REVIEWS, 2005, 249 (21-22) :2534-2548

[5]

Nakamoto N., 1986, Infrared spectra of inorganic coordination compounds, V4th

[6] Separation of hydrocarbons with a microporous metal-organic framework [J].

Pan, L ;

Olson, DH ;

Ciemnolonski, LR ;

Heddy, R ;

Li, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (04) :616-619

[7] Zn(tbip) (H2tbip=5-tert-butyl isophthalic acid):: A highly stable guest-free microporous metal organic framework with unique gas separation capability [J].

Pan, L ;

Parker, B ;

Huang, XY ;

Olson, DH ;

Lee, J ;

Li, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (13) :4180-4181

[8]

Sheldrick G.M., 1997, SHELXS 97 SHELXL 97

[9] Engineering of non-interpenetrating 3-D and 2-D networks and guest adsorption based on 4,4′-di(3-methyl)pyridyl sulfide copper(II) complexes [J].

Su, XC ;

Zhu, SR ;

Lin, HK ;

Leng, XB ;

Chen, YT .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (21) :3163-3168

[10] Chiral polyoxometalate-induced enantiomerically 3D architectures: A new route for synthesis of high-dimensional chiral compounds [J].

Tan, Huaqiao ;

Li, Yangguang ;

Zhang, Zhiming ;

Qin, Chao ;

Wang, Xinlong ;

Wang, Enbo ;

Su, Zhongmin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (33) :10066-10067

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