Copper and zinc complexes with 2,3-pyridinedicarboxylic acid or 2,3-pyrazinedicarboxylic acid: Polymer structures and magnetic properties

被引：51

作者：

Yin, Hua

Liu, Shi-Xiong ^{[1
]}

机构：

[1] Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2009年 / 918卷 / 1-3期

关键词：

2,3-Pyridinedicarboxylic acid; 2,3-Pyrazinedicarboxylic acid; Copper complex; Zinc complex; Crystal structure; COORDINATION POLYMERS; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURES; DONOR LIGANDS; PHOTOLUMINESCENCE; PYRIDINE-2,3-DICARBOXYLATE; ARCHITECTURES; CHAIN; MOTIF;

D O I：

10.1016/j.molstruc.2008.07.033

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Six title copper(II)/zinc(II) coordination polymers have been synthesized, using the metal salt with different oxidation states (Cu(NO3)(2)/CuBr2/CuI/Zn(OAc)(2)), dicarboxylate ligand (2,3-pyridinedicarboxylic acid (pydc) or 2,3-pyrazinedicarboxylic acid (pzdc)) and the auxiliary ligand (2,2'-bpy, phen or 4,4'-bpy). The dicarboxylate ligand (pydc or pzdc) bridges two neighboring metal atoms to form a 1D chain in complexes 1, 2. 3, 4 and 6 and 2D network in 5, respectively. There are an extended 3D metal-organic framework in 1-5 and an extended 2D network in 6, respectively. The magnetic properties and phololuminescent property of some title complexes were investigated. The factors affecting structural characterizations in the products have been discussed. (C) 2008 Elsevier B.V. All rights reserved.

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页码：165 / 173

页数：9

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