Facile synthesis of nitrogen-doped mesoporous hollow carbon nanospheres@NiCo2O4for high-performance supercapacitors

被引:4
作者
Wang, Zhongbing [1 ,2 ]
Hao, Yonghao [1 ]
Qiang, Hongwen [1 ]
Xu, Chao [1 ]
Chen, Chunnian [1 ]
机构
[1] Hefei Univ Technol, Sch Chem & Chem Engn, Hefei 230009, Peoples R China
[2] Anhui Prov Engn Technol Res Ctr Water Borne Polym, Hefei 230601, Peoples R China
关键词
Hollow carbon; NiCo2O4; MOF materials; Supercapacitors; ENHANCED ELECTROCHEMICAL PERFORMANCE; ELECTRODE MATERIAL; NICO2O4; NANOSTRUCTURES; GRAPHENE; MICROSPHERES; NANOSHEETS; NANOLAYER; SPHERES;
D O I
10.1007/s11581-020-03794-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Highly performance composite material nitrogen-doped mesoporous hollow carbon nanospheres and Ni-Co coordination polymer metal precursor (N-MHCNS700@Ni-Co-MOF) obtained by using hydrothermal reaction Ni-Co coordination polymer metal precursor to assist hollow carbon nanospheres as templates. Then the composite material (N-MHCNS700@Ni-Co-MOF) is calcined under nitrogen to obtain nitrogen-doped mesoporous hollow carbon nanospheres and nickel cobalt metal oxide (N-MHCNS700@NiCo2O4). Material characterization is used to analyze the morphology and structure of the material. The hybrid materials exhibit high specific capacitance (166 mAh g(-1)at 1 A g(-1)) and great cyclic stability (approximately 85.6% retained after 5,000 cycles at 10 A g(-1)). The composite material also have outstanding power density of composite (624.9 W kg(-1)) and the energy density (42.8 Wh kg(-1)). Therefore, composite materials can be applied to electrode materials for high-performance supercapacitor.
引用
收藏
页码:315 / 323
页数:9
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