Regioselective and enantiospecific rhodium-catalyzed allylic amination with thymine: synthesis of a new conformationally rigid nucleoside

被引：25

作者：

Evans, PA ^{[1
]}

Lai, KW ^{[1
]}

Zhang, HR ^{[1
]}

Huffman, JC ^{[1
]}

机构：

[1] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 08期

关键词：

D O I：

10.1039/b513083b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The regioselective and enantiospecific rhodium-catalyzed allylic amination of secondary allylic carbonates with N-3-benzoyl thymine in conjunction with a stereoselective free radical cyclization provides a convenient method for the construction of a new conformationally rigid nucleoside.

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收藏

页码：844 / 846

页数：3

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