An efficient and reusable "hairy" particle acid catalyst for the synthesis of 5-hydroxymethylfurfural from dehydration of fructose in water

被引：42
作者：
Tian, Chengcheng [1 ,2 ,3 ]
Bao, Chunhui [3 ]
Binder, Andrew [3 ]
Zhu, Zhenqian [3 ]
Hu, Bin [3 ]
Guo, Yanglong [1 ]
Zhao, Bin [3 ]
Dai, Sheng [2 ,3 ]
机构：
[1] E China Univ Sci & Technol, Res Inst Ind Catalysis, Key Lab Adv Mat, Shanghai 200237, Peoples R China
[2] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA
[3] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 77期
基金：
美国国家科学基金会;
关键词：
MIXED HOMOPOLYMER BRUSHES; SILICA; BIOMASS; POLYMERIZATION; DESIGN;
D O I：
10.1039/c3cc43127d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Poly(4-styrenesulfonic acid) brush-grafted silica particles, synthesized by surface-initiated atom transfer radical polymerization, were employed as a reusable acid catalyst for dehydration of fructose to 5-hydroxymethylfurfural (HMF) in water. The particles exhibited a high activity with the HMF yield of up to 31%, in contrast to 26% from the corresponding free homopolymer catalyst.
引用
收藏
页码：8668 / 8670
页数：3
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