The elastic and optical properties of a bent-core thiadiazole nematic liquid crystal: the role of the bend angle

被引:44
作者
Kaur, S. [1 ]
Tian, L. [1 ]
Liu, H. [1 ]
Greco, C. [2 ]
Ferrarini, A. [2 ]
Seltmann, J. [3 ]
Lehmannd, M. [4 ]
Gleeson, H. F. [1 ]
机构
[1] Univ Manchester, Sch Phys & Astron, Manchester M13 9PL, Lancs, England
[2] Univ Padua, Dept Chem Sci, I-35131 Padua, Italy
[3] Tech Univ Chemnitz, Inst Chem, D-09111 Chemnitz, Germany
[4] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany
基金
英国工程与自然科学研究理事会;
关键词
BIREFRINGENCE; ANISOTROPY; MIXTURES; MOLECULES; CONSTANTS; VISCOSITY; PHASE;
D O I
10.1039/c3tc00852e
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The elastic and optical properties of a bent-core thiadiazole nematic liquid crystal are reported. The system exhibits unusually large values of birefringence (similar to 0.4), which can be partly attributed to significant conjugation in the molecular structure. It is found that the splay (K-11), twist (K-22) and bend (K-33) elastic constants, determined from studies of the Freedericksz transition, satisfy K-33 > K-11 > K-22 across the wide nematic range studied. Such behaviour is analogous to that commonly observed in calamitic nematic liquid crystals but is in contrast to all other bent-core nematic materials reported to date where it is found that K-33 < K-11. Such a result questions some of the current explanations that have been put forward to explain the elastic behaviour of bent-core materials. Using a molecular field theory, combined with DFT calculations of the molecular structure, we can ascribe the different elastic behaviour to the value of the bend angle in the molecular core. This angle is shown to play a subtle and substantial role in determining the physical properties of bent-core nematic liquid crystals.
引用
收藏
页码:2416 / 2425
页数:10
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