Tetravalent and pentavalent uranium acetylide complexes prepared by oxidative functionalization with CuCCPh

被引：71
|
作者：
Graves, Christopher R. [1 ]
Scott, Brian L. [1 ]
Morris, David E. [1 ]
Kiplinger, Jaqueline L. [1 ]
机构：
[1] Los Alamos Natl Lab, Los Alamos, NM 87545 USA
来源：
ORGANOMETALLICS | 2008年 / 27卷 / 14期
关键词：
D O I：
10.1021/om800466m
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Oxidation of(C5Me5)(2)U(NPh2)(THF) and(C5Me5)(2)U(=N-2,6-Pr-i(2)-C6H3)(THF) with CuC CPh yields the corresponding U-IV and U-V aceolide complexes (C5Me5)(2)U(NPh2)(C CPh) and (C5Me5)(2)U(=N-2,6-Pr-i(2)-C6H3)(C CPh), respectively. The complexes were characterized using a combination of H-1 NMR, X-ray crystallography, UV-visible-near-IR spectroscopy, and cyclic voltammetry.
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页码：3335 / 3337
页数：3
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