Effective interplay of donor and acceptor groups for tuning optoelectronic properties in oligothiophene-naphthalimide assemblies

被引：18

作者：

Alonso-Navarro, Matias J. ^{[1
,2
]}

Harbuzaru, Alexandra ^{[3
]}

de Echegaray, Paula ^{[1
,2
]}

Arrechea-Marcos, Iratxe ^{[3
]}

Harillo-Banos, Albert ^{[4
]}

de la Pena, Alejandro ^{[1
,2
]}

Ramos, M. Mar ^{[2
]}

Lopez Navarrete, J. Teodomiro ^{[3
]}

Campoy-Quiles, Mariano ^{[4
]}

Ponce Ortiz, Rocio ^{[3
]}

Segura, Jose L. ^{[1
]}

机构：

[1] Univ Complutense Madrid, Fac Chem, Dept Organ Chem, Madrid 28040, Spain

[2] Univ Rey Juan Carlos, Chem & Environm Technol Dept, Mostoles 28933, Spain

[3] Univ Malaga, Dept Phys Chem, Malaga 29071, Spain

[4] Inst Ciencia Mat Barcelona ICMAB CSIC, Bellaterra 08193, Spain

来源：

JOURNAL OF MATERIALS CHEMISTRY C | 2020年 / 8卷 / 43期

关键词：

FIELD-EFFECT TRANSISTORS; N-TYPE; ORGANIC SEMICONDUCTORS; ELECTRON-ACCEPTOR; HIGH-PERFORMANCE; CHARGE-TRANSFER; SOLAR-CELLS; MOBILITY; EFFICIENT; POLYMER;

D O I：

10.1039/d0tc03026k

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

In this work, a series of naphthalimide fused thienopyrazine derivatives was designed, and their synthesis and characterization are reported herein. The interaction of this building block with a donor terthiophene fragment laterally substituted by a series of donor and acceptor constituents was analyzed in depth. This strategy was proven to efficiently modulate both the energy and topology of the frontier molecular orbitals involved in the charge transport mechanism. The interplay between the donor and acceptor strengths of the different units composing the material structure is thus essential to efficiently modulate charge carriers and transport properties and to finely tune the optical and electronic structures of the presented organic semiconductors.

引用

页码：15277 / 15289

页数：13

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