Transport coefficients of typical biomass equimolar CO-H2 plasma

被引:24
作者
Aubreton, J. [1 ]
Elchinger, M-F [1 ]
Hacala, A. [2 ]
Michon, U. [2 ]
机构
[1] Univ Limoges, CNRS, SPCTS, UMR6638, 123 Ave Albert Tomas, F-87060 Limoges, France
[2] EUROPLASMA, F-33100 Bordeaux, France
关键词
ENERGY-ELECTRON SCATTERING; ARGON-HYDROGEN PLASMAS; COLLISION INTEGRALS; DIPOLE POLARIZABILITIES; INTERATOMIC FORCES; CROSS-SECTIONS; CARBON-DIOXIDE; CO; MOLECULES; DIFFUSION;
D O I
10.1088/0022-3727/42/9/095206
中图分类号
O59 [应用物理学];
学科分类号
摘要
Knowledge of the transport properties of biomass gases is important for modelling plasma flow processes and heat transfer. In this study, calculations were performed for typical biomass equimolar CO-H-2 plasma in a temperature range from 500 to 30000K at pressures of 1.0, 2.0, 5.0 and 10.0 bar. Herein, the plasma composition was determined at equilibrium using the Gibbs free energy equation. First, we restricted the species number to 18 for CO-H-2 plasma. Second, the most recent data on potential interactions and elastic differential cross sections were carefully investigated in order to choose those most appropriate to define the collision integrals. Due to a lack of data we used an improvement of the Lennard-Jones function. Third, we tested our collision integrals by comparing (1) the viscosity to experimental data of CO2, CH4 and CO (low temperature) and (2) the thermal conductivity and vicosity to theoretical results for CO2 plasma (up to 17 000 K). Finally, the viscosity, thermal conductivity and electrical conductivity were calculated for different pressures.
引用
收藏
页数:13
相关论文
共 68 条
[1]   EXPONENTIAL-ALPHA-6 POTENTIAL PARAMETERS FROM AB-INITIO CALCULATIONS FOR ATOM MOLECULE INTERACTIONS [J].
AMAEE, B ;
BROWN, WB .
CHEMICAL PHYSICS, 1993, 174 (03) :351-365
[2]  
[Anonymous], 1953, The Mathematical Theory of Non-Uniform Gases
[3]   Range and strength of interatomic forces: Dispersion and induction contributions to the bonds of dications and of ionic molecules [J].
Aquilanti, V ;
Cappelletti, D ;
Pirani, F .
CHEMICAL PHYSICS, 1996, 209 (2-3) :299-311
[4]   Transport Coefficients in Water Plasma: Part I: Equilibrium Plasma [J].
Aubreton, J. ;
Elchinger, M. F. ;
Vinson, J. M. .
PLASMA CHEMISTRY AND PLASMA PROCESSING, 2009, 29 (02) :149-171
[5]  
BOISSONNET G, 2003, CEAR6025
[6]   Electronic structure and dynamics of O(3P)+CO(1Σ+) collisions [J].
Braunstein, M ;
Duff, JW .
JOURNAL OF CHEMICAL PHYSICS, 2000, 112 (06) :2736-2745
[7]   Low-energy electron scattering from methane [J].
Bundschu, CT ;
Gibson, JC ;
Gulley, RJ ;
Brunger, MJ ;
Buckman, SJ ;
Sanna, N ;
Gianturco, FA .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1997, 30 (09) :2239-2259
[8]   EQUILIBRIUM AND TRANSPORT-PROPERTIES OF GAS-MIXTURES AT LOW-DENSITY - 11 POLYATOMIC GASES AND 5 NOBLE-GASES [J].
BZOWSKI, J ;
KESTIN, J ;
MASON, EA ;
URIBE, FJ .
JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1990, 19 (05) :1179-1232
[9]   GENERALIZED CORRELATIONS IN TERMS OF POLARIZABILITY FOR VANDERWAALS INTERACTION POTENTIAL PARAMETER CALCULATIONS [J].
CAMBI, R ;
CAPPELLETTI, D ;
LIUTI, G ;
PIRANI, F .
JOURNAL OF CHEMICAL PHYSICS, 1991, 95 (03) :1852-1861
[10]   On the possibility of using model potentials for collision integral calculations of interest for planetary atmospheres [J].
Capitelli, M. ;
Cappelletti, D. ;
Colonna, G. ;
Gorse, C. ;
Laricchiuta, A. ;
Liuti, G. ;
Longo, S. ;
Pirani, F. .
CHEMICAL PHYSICS, 2007, 338 (01) :62-68