In situ tandem allylic acetate isomerisation-ring closing metathesis: 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene ruthenium benzylidenes and palladium(0)-phosphine combinations

被引：36

作者：

Braddock, DC ^{[1
]}

Matsuno, A ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 18期

关键词：

allylic isomerisation; palladium(0); ruthenium benzylidene; 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene; olefin metathesis;

D O I：

10.1016/S0040-4039(02)00526-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The use of 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene ruthenium benzylidenes as olefin metathesis pre-catalysts in conjunction with palladium(0) phosphine combinations allows tandem in situ allylic acetate isomerisation ring closing metathesis reactions to occur. The tandem reaction can either be performed on separate substrates in the same pot, or on substrates containing both allylic acetate and diene functionality. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：3305 / 3308

页数：4

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