Iodine-Mediated Highly Regio- and Stereoselective Iodoamination of Ferrocenyl Allene: An Approach for the Synthesis of Ferrocene-Containing Allylic Amines

被引：18

作者：

Chen, Shufeng ^{[1
]}

Yan, Qing ^{[1
]}

Zhao, Haiying ^{[1
]}

Li, Baoguo ^{[1
]}

机构：

[1] Inner Mongolia Univ, Coll Chem & Chem Engn, Hohhot 010021, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 78卷 / 10期

基金：

中国国家自然科学基金;

关键词：

EFFICIENT SYNTHESIS; BIOORGANOMETALLIC CHEMISTRY; 1,2-ALLENYL SULFIDES; SUBSTITUTED ALLENES; PHENYL SULFOXIDES; ORGANIC-SYNTHESIS; IODOHYDROXYLATION; HALOHYDROXYLATION; FUNCTIONALITY; SELENIDES;

D O I：

10.1021/jo4006206

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A straightforward and efficient protocol for the highly regio- and stereoselective synthesis of ferrocene-containing allylic amine derivatives via an iodine-mediated iodoamination of ferrocenyl allene was developed. The regio- and stereoselectivity of this reaction may be controlled by the steric effect of the bulky ferrocene group.

引用

页码：5085 / 5089

页数：5

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